Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials
Giant dielectric material CaCu3Ti4O12 (CCTO) has found widespread applications, but associated high dielectric loss is still a major concern. The decreasing of dielectric tangent loss (tan δ) via rare earth element doping has been proven to be effective strategy, but in most cases it involves comple...
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University of Novi Sad
2020-09-01
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doaj-a92a96cc00dc46edb7c6b7c33469dae32020-11-25T01:24:14ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312406-10342020-09-0114324225010.2298/PAC2003242SProcessing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materialsArindam Sen0Department of Electronics, Bankura Christian College, Bankura-722101, West Bengal, IndiaGiant dielectric material CaCu3Ti4O12 (CCTO) has found widespread applications, but associated high dielectric loss is still a major concern. The decreasing of dielectric tangent loss (tan δ) via rare earth element doping has been proven to be effective strategy, but in most cases it involves complex and time consuming processing. In the present paper, a fast and facile process is reported for the synthesis of lanthanum doped CCTO powders (Ca1-xLaxCu3Ti4O12 where x = 0.0, 0.05 and 0.1) using molten eutectic mixture as the reaction medium. The obtained powders were pressed and finally sintered at 1050 °C. La3+ substitution at Ca2+ site results in remarkable reduction in dielectric loss (tan δ < 0.03) at room temperature compared to the parent CCTO. The increased grain boundary resistance (Rgb) estimated from room temperature complex impedance plane plot (Z∗) for the doped ceramics is proposed to be the major cause for higher thermal stability of dielectric constant (εr) and remarkable reduction in tan δ at room temperature. Furthermore, the frequency and temperature stability of εr and tan δ over wide ranges make the doped CCTO a promising candidate for high temperature ceramic capacitor application.http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2049%2009.pdfcacu3ti4o12 ceramicsdielectric propertiesmicrostructureperovskitessintering |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Arindam Sen |
spellingShingle |
Arindam Sen Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials Processing and Application of Ceramics cacu3ti4o12 ceramics dielectric properties microstructure perovskites sintering |
author_facet |
Arindam Sen |
author_sort |
Arindam Sen |
title |
Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
title_short |
Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
title_full |
Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
title_fullStr |
Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
title_full_unstemmed |
Processing of lanthanum doped CaCu3Ti4O12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
title_sort |
processing of lanthanum doped cacu3ti4o12 electroceramics in molten eutectic mixture for low loss high dielectric materials |
publisher |
University of Novi Sad |
series |
Processing and Application of Ceramics |
issn |
1820-6131 2406-1034 |
publishDate |
2020-09-01 |
description |
Giant dielectric material CaCu3Ti4O12 (CCTO) has found widespread applications, but associated high dielectric loss is still a major concern. The decreasing of dielectric tangent loss (tan δ) via rare earth element doping has been proven to be effective strategy, but in most cases it involves complex and time consuming processing. In the present paper, a fast and facile process is reported for the synthesis of lanthanum doped CCTO powders (Ca1-xLaxCu3Ti4O12 where x = 0.0, 0.05 and 0.1) using molten eutectic mixture as the reaction medium. The obtained powders were pressed and finally sintered at 1050 °C. La3+ substitution at Ca2+ site results in remarkable reduction in dielectric loss (tan δ < 0.03) at room temperature compared to the parent CCTO. The increased grain boundary resistance (Rgb) estimated from room temperature complex impedance plane plot (Z∗) for the doped ceramics is proposed to be the major cause for higher thermal stability of dielectric constant (εr) and remarkable reduction in tan δ at room temperature. Furthermore, the frequency and temperature stability of εr and tan δ over wide ranges make the doped CCTO a promising candidate for high temperature ceramic capacitor application. |
topic |
cacu3ti4o12 ceramics dielectric properties microstructure perovskites sintering |
url |
http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2049%2009.pdf |
work_keys_str_mv |
AT arindamsen processingoflanthanumdopedcacu3ti4o12electroceramicsinmolteneutecticmixtureforlowlosshighdielectricmaterials |
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1725118190401355776 |