MCM-41 Porosity: Are Surface Corrugations Micropores?
Since the discovery of MCM-41, the interpretation of its structure and porous texture has evolved from a simple model of straight parallel mesopores to a much more complex model with a rough surface. The physisorption of nitrogen at 77.3 K and 87.5 K and of carbon dioxide at 273 K was carried out on...
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2011-06-01
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Online Access: | https://doi.org/10.1260/0263-6174.29.5.443 |
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doaj-a9316bdf4ccc4a1ab04faf20f5f5a36e2021-04-02T13:34:31ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40382011-06-012910.1260/0263-6174.29.5.443MCM-41 Porosity: Are Surface Corrugations Micropores?Ángel Berenguer-MurciaDiego Cazorla-AmorósÁngel Linares-SolanoSince the discovery of MCM-41, the interpretation of its structure and porous texture has evolved from a simple model of straight parallel mesopores to a much more complex model with a rough surface. The physisorption of nitrogen at 77.3 K and 87.5 K and of carbon dioxide at 273 K was carried out on both MCM-41 and a precipitated silica (PSIL). This silica was prepared for comparison purposes under identical conditions to those for MCM-41 but without the use of the surfactant. The adsorption characteristics of both materials for both adsorptives were indistinguishable at low adsorption pressures independent of the adsorption temperature employed, suggesting similarities in parts of their porosity (i.e. excluding mesoporosity). We propose that, in addition to its well-acknowledged mesoporosity, MCM-41 includes considerable surface roughness and/or heterogeneities similar to that shown by microporous silica. This surface structure appears to have adsorption characteristics indistinguishable from classical microporosity, and may also be an important feature of this material which is very often not taken into consideration in most of its applications.https://doi.org/10.1260/0263-6174.29.5.443 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ángel Berenguer-Murcia Diego Cazorla-Amorós Ángel Linares-Solano |
spellingShingle |
Ángel Berenguer-Murcia Diego Cazorla-Amorós Ángel Linares-Solano MCM-41 Porosity: Are Surface Corrugations Micropores? Adsorption Science & Technology |
author_facet |
Ángel Berenguer-Murcia Diego Cazorla-Amorós Ángel Linares-Solano |
author_sort |
Ángel Berenguer-Murcia |
title |
MCM-41 Porosity: Are Surface Corrugations Micropores? |
title_short |
MCM-41 Porosity: Are Surface Corrugations Micropores? |
title_full |
MCM-41 Porosity: Are Surface Corrugations Micropores? |
title_fullStr |
MCM-41 Porosity: Are Surface Corrugations Micropores? |
title_full_unstemmed |
MCM-41 Porosity: Are Surface Corrugations Micropores? |
title_sort |
mcm-41 porosity: are surface corrugations micropores? |
publisher |
Hindawi - SAGE Publishing |
series |
Adsorption Science & Technology |
issn |
0263-6174 2048-4038 |
publishDate |
2011-06-01 |
description |
Since the discovery of MCM-41, the interpretation of its structure and porous texture has evolved from a simple model of straight parallel mesopores to a much more complex model with a rough surface. The physisorption of nitrogen at 77.3 K and 87.5 K and of carbon dioxide at 273 K was carried out on both MCM-41 and a precipitated silica (PSIL). This silica was prepared for comparison purposes under identical conditions to those for MCM-41 but without the use of the surfactant. The adsorption characteristics of both materials for both adsorptives were indistinguishable at low adsorption pressures independent of the adsorption temperature employed, suggesting similarities in parts of their porosity (i.e. excluding mesoporosity). We propose that, in addition to its well-acknowledged mesoporosity, MCM-41 includes considerable surface roughness and/or heterogeneities similar to that shown by microporous silica. This surface structure appears to have adsorption characteristics indistinguishable from classical microporosity, and may also be an important feature of this material which is very often not taken into consideration in most of its applications. |
url |
https://doi.org/10.1260/0263-6174.29.5.443 |
work_keys_str_mv |
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