Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of al...
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The Royal Society
2018-01-01
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Online Access: | https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541 |
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doaj-a9360ee0b6234cffb68e4617748ec1472020-11-25T04:06:38ZengThe Royal SocietyRoyal Society Open Science2054-57032018-01-015510.1098/rsos.171541171541Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditionsM. KazemnejadiA. ShakeriM. NikookarR. ShademaniM. MohammadiPolydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of alkenes with dioxirane groups than before. PDOX can be simply recovered from the reaction mixture by plain filtration and reused for eight runs without significant reactivity loss.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541epoxidationpolysalicylaldehydepolydioxiraneterminal alkenerecoverabilitymild conditions |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
M. Kazemnejadi A. Shakeri M. Nikookar R. Shademani M. Mohammadi |
spellingShingle |
M. Kazemnejadi A. Shakeri M. Nikookar R. Shademani M. Mohammadi Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions Royal Society Open Science epoxidation polysalicylaldehyde polydioxirane terminal alkene recoverability mild conditions |
author_facet |
M. Kazemnejadi A. Shakeri M. Nikookar R. Shademani M. Mohammadi |
author_sort |
M. Kazemnejadi |
title |
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
title_short |
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
title_full |
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
title_fullStr |
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
title_full_unstemmed |
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
title_sort |
selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions |
publisher |
The Royal Society |
series |
Royal Society Open Science |
issn |
2054-5703 |
publishDate |
2018-01-01 |
description |
Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of alkenes with dioxirane groups than before. PDOX can be simply recovered from the reaction mixture by plain filtration and reused for eight runs without significant reactivity loss. |
topic |
epoxidation polysalicylaldehyde polydioxirane terminal alkene recoverability mild conditions |
url |
https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541 |
work_keys_str_mv |
AT mkazemnejadi selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions AT ashakeri selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions AT mnikookar selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions AT rshademani selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions AT mmohammadi selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions |
_version_ |
1724431250962251776 |