Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions

Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of al...

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Main Authors: M. Kazemnejadi, A. Shakeri, M. Nikookar, R. Shademani, M. Mohammadi
Format: Article
Language:English
Published: The Royal Society 2018-01-01
Series:Royal Society Open Science
Subjects:
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541
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spelling doaj-a9360ee0b6234cffb68e4617748ec1472020-11-25T04:06:38ZengThe Royal SocietyRoyal Society Open Science2054-57032018-01-015510.1098/rsos.171541171541Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditionsM. KazemnejadiA. ShakeriM. NikookarR. ShademaniM. MohammadiPolydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of alkenes with dioxirane groups than before. PDOX can be simply recovered from the reaction mixture by plain filtration and reused for eight runs without significant reactivity loss.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541epoxidationpolysalicylaldehydepolydioxiraneterminal alkenerecoverabilitymild conditions
collection DOAJ
language English
format Article
sources DOAJ
author M. Kazemnejadi
A. Shakeri
M. Nikookar
R. Shademani
M. Mohammadi
spellingShingle M. Kazemnejadi
A. Shakeri
M. Nikookar
R. Shademani
M. Mohammadi
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
Royal Society Open Science
epoxidation
polysalicylaldehyde
polydioxirane
terminal alkene
recoverability
mild conditions
author_facet M. Kazemnejadi
A. Shakeri
M. Nikookar
R. Shademani
M. Mohammadi
author_sort M. Kazemnejadi
title Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
title_short Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
title_full Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
title_fullStr Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
title_full_unstemmed Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
title_sort selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions
publisher The Royal Society
series Royal Society Open Science
issn 2054-5703
publishDate 2018-01-01
description Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated. This work also introduced a simpler, safer and milder way for epoxidation of alkenes with dioxirane groups than before. PDOX can be simply recovered from the reaction mixture by plain filtration and reused for eight runs without significant reactivity loss.
topic epoxidation
polysalicylaldehyde
polydioxirane
terminal alkene
recoverability
mild conditions
url https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.171541
work_keys_str_mv AT mkazemnejadi selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions
AT ashakeri selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions
AT mnikookar selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions
AT rshademani selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions
AT mmohammadi selectiveandmetalfreeepoxidationofterminalalkenesbyheterogeneouspolydioxiraneinmildconditions
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