Bis[benzyl N′-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-κ2N′,S]nickel(II) N,N-dimethylformamide disolvate
In the title compound, [Ni(C17H14N3S2)2]·2C3H7NO, the Ni atom (site symmetry overline{1}) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808038580 |
| Summary: | In the title compound, [Ni(C17H14N3S2)2]·2C3H7NO, the Ni atom (site symmetry overline{1}) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N—H...O hydrogen bond links the complex to the dimethylformamide solvent molecule. |
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| ISSN: | 1600-5368 |