(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the t...

Full description

Bibliographic Details
Main Authors: Dame Seye, Cheikh Abdoul Khadir Diop, Libasse Diop, David Renald
Format: Article
Language:English
Published: International Union of Crystallography 2016-11-01
Series:IUCrData
Subjects:
crystal structure
SnC3O2 coordination
trigonal-bipyramidal environment
intramolecular hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461601840X
Description
Summary:The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the three ipso C atoms occupy the equatorial positions. An intramolecular O—H...O hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.
ISSN:2414-3146

Similar Items