(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the t...

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Bibliographic Details
Main Authors: Dame Seye, Cheikh Abdoul Khadir Diop, Libasse Diop, David Renald
Format: Article
Language:English
Published: International Union of Crystallography 2016-11-01
Series:IUCrData
Subjects:
crystal structure
SnC3O2 coordination
trigonal-bipyramidal environment
intramolecular hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461601840X
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spelling doaj-a9d9db816dce49d8aaa9087a2e4a60572020-11-24T21:32:20ZengInternational Union of CrystallographyIUCrData2414-31462016-11-01111x16184010.1107/S241431461601840Xwm4029(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)Dame Seye0Cheikh Abdoul Khadir Diop1Libasse Diop2David Renald3Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Réactivité et Chimie des Solides (LRCS), Université de Picardie Jules Verne, CNRS UMR 7314, 33 rue Saint Leu, 80039 Amiens, FranceThe title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the three ipso C atoms occupy the equatorial positions. An intramolecular O—H...O hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.http://scripts.iucr.org/cgi-bin/paper?S241431461601840Xcrystal structureSnC3O2 coordinationtrigonal-bipyramidal environmentintramolecular hydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Dame Seye
Cheikh Abdoul Khadir Diop
Libasse Diop
David Renald
spellingShingle Dame Seye
Cheikh Abdoul Khadir Diop
Libasse Diop
David Renald
(2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
IUCrData
crystal structure
SnC3O2 coordination
trigonal-bipyramidal environment
intramolecular hydrogen bonding
author_facet Dame Seye
Cheikh Abdoul Khadir Diop
Libasse Diop
David Renald
author_sort Dame Seye
title (2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
title_short (2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
title_full (2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
title_fullStr (2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
title_full_unstemmed (2-Hydroxybenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)
title_sort (2-hydroxybenzoato-κo)triphenyl(triphenylphosphine oxide-κo)tin(iv)
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-11-01
description The title compound, [Sn{C6H4(OH)COO}(C6H5)3{OP(C6H5)3}], is comprised of discrete molecules with the SnIV atom in a trigonal–bipyramidal coordination environment. The carboxylate O atom of the salicylate anion and the O atom of the triphenylphosphine oxide moiety are in the axial positions and the three ipso C atoms occupy the equatorial positions. An intramolecular O—H...O hydrogen bond is present in the anion between the hydroxy group and the carbonyl atom O of the carboxylate group.
topic crystal structure
SnC3O2 coordination
trigonal-bipyramidal environment
intramolecular hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S241431461601840X
work_keys_str_mv AT dameseye 2hydroxybenzoatokotriphenyltriphenylphosphineoxidekotiniv
AT cheikhabdoulkhadirdiop 2hydroxybenzoatokotriphenyltriphenylphosphineoxidekotiniv
AT libassediop 2hydroxybenzoatokotriphenyltriphenylphosphineoxidekotiniv
AT davidrenald 2hydroxybenzoatokotriphenyltriphenylphosphineoxidekotiniv
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