Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies

The use of low-cost, easily obtained and eco-friendly adsorbents has been employed as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of activated carbons such as aamla seed carbon (ASC), jambul seed carbon (JSC), tama...

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Main Authors: K. Shahul Hameed, P. Muthirulan, M. Meenakshi Sundaram
Format: Article
Language:English
Published: Elsevier 2017-05-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S187853521300258X
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spelling doaj-aa4fc44e37f04230b0703848adfadd782020-11-25T00:12:21ZengElsevierArabian Journal of Chemistry1878-53522017-05-0110S2S2225S223310.1016/j.arabjc.2013.07.058Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studiesK. Shahul Hameed0P. Muthirulan1M. Meenakshi Sundaram2Department of Chemistry, Hajee Karutha Rowther Howdia College, Uthamapalayam, IndiaCentre for Research and Post-Graduate Studies in Chemistry, Ayya Nadar Janaki Ammal College (Autonomus), Sivakasi 626124, IndiaCentre for Research and Post-Graduate Studies in Chemistry, Ayya Nadar Janaki Ammal College (Autonomus), Sivakasi 626124, IndiaThe use of low-cost, easily obtained and eco-friendly adsorbents has been employed as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of activated carbons such as aamla seed carbon (ASC), jambul seed carbon (JSC), tamarind seed carbon (TSC) and soapnut carbon (SNC) for the removal of chromotrope (CH) dye from simulated wastewater. The obtained results were compared with that of Commercial Activated Carbon (CAC). The effects of different system variables, adsorbent dosage, pH and particle size were studied. The results showed that as the amount of the adsorbent increased, the amount adsorbed per unit mass decreased accordingly. Optimum pH value for dye adsorption was determined as ∼2.0. The adsorption of chromotrope fit well into pseudo-second-order rate equation. The adsorption also obeyed Langmuir and Redlich–Peterson equations better than Temkin, Freundlich and Dubinin–Radushkevich (D–R) equations. The adsorption capacities of low cost adsorbents were found to be in the following order ASC > JSC > TSC > SNC. The activated carbons prepared were characterized by FT-IR and SEM analysis.http://www.sciencedirect.com/science/article/pii/S187853521300258XAdsorptionChromotrope (CH)Aamla seed carbon (ASC)Jambul seed carbon (JSC)Tamarind seed carbon (TSC)Soapnut carbon (SNC)Commercial activated carbon (CAC)
collection DOAJ
language English
format Article
sources DOAJ
author K. Shahul Hameed
P. Muthirulan
M. Meenakshi Sundaram
spellingShingle K. Shahul Hameed
P. Muthirulan
M. Meenakshi Sundaram
Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
Arabian Journal of Chemistry
Adsorption
Chromotrope (CH)
Aamla seed carbon (ASC)
Jambul seed carbon (JSC)
Tamarind seed carbon (TSC)
Soapnut carbon (SNC)
Commercial activated carbon (CAC)
author_facet K. Shahul Hameed
P. Muthirulan
M. Meenakshi Sundaram
author_sort K. Shahul Hameed
title Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
title_short Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
title_full Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
title_fullStr Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
title_full_unstemmed Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies
title_sort adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: equilibrium and kinetics studies
publisher Elsevier
series Arabian Journal of Chemistry
issn 1878-5352
publishDate 2017-05-01
description The use of low-cost, easily obtained and eco-friendly adsorbents has been employed as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of activated carbons such as aamla seed carbon (ASC), jambul seed carbon (JSC), tamarind seed carbon (TSC) and soapnut carbon (SNC) for the removal of chromotrope (CH) dye from simulated wastewater. The obtained results were compared with that of Commercial Activated Carbon (CAC). The effects of different system variables, adsorbent dosage, pH and particle size were studied. The results showed that as the amount of the adsorbent increased, the amount adsorbed per unit mass decreased accordingly. Optimum pH value for dye adsorption was determined as ∼2.0. The adsorption of chromotrope fit well into pseudo-second-order rate equation. The adsorption also obeyed Langmuir and Redlich–Peterson equations better than Temkin, Freundlich and Dubinin–Radushkevich (D–R) equations. The adsorption capacities of low cost adsorbents were found to be in the following order ASC > JSC > TSC > SNC. The activated carbons prepared were characterized by FT-IR and SEM analysis.
topic Adsorption
Chromotrope (CH)
Aamla seed carbon (ASC)
Jambul seed carbon (JSC)
Tamarind seed carbon (TSC)
Soapnut carbon (SNC)
Commercial activated carbon (CAC)
url http://www.sciencedirect.com/science/article/pii/S187853521300258X
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AT pmuthirulan adsorptionofchromotropedyeontoactivatedcarbonsobtainedfromtheseedsofvariousplantsequilibriumandkineticsstudies
AT mmeenakshisundaram adsorptionofchromotropedyeontoactivatedcarbonsobtainedfromtheseedsofvariousplantsequilibriumandkineticsstudies
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