Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas

Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas

V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> catalysts with different V<sub>2</sub>O<sub>5</sub> and WO<sub>3</sub> loadings were prepared by the impregnation method. H<sub>2</sub>O and SO<...

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Main Authors: Ruliang Ning, Li Chen, Erwei Li, Xiaolong Liu, Tingyu Zhu
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Catalysts
Subjects:
selective catalytic reduction
V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub>
H<sub>2</sub>O and SO<sub>2</sub> resistance
basic metals
Online Access:https://www.mdpi.com/2073-4344/9/3/220
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spelling doaj-aa84dba0254c4c9eb1c2133bf253776a2020-11-25T01:33:49ZengMDPI AGCatalysts2073-43442019-02-019322010.3390/catal9030220catal9030220Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue GasRuliang Ning0Li Chen1Erwei Li2Xiaolong Liu3Tingyu Zhu4Beijing Engineering Research Center of Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing Engineering Research Center of Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing Engineering Research Center of Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing Engineering Research Center of Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing Engineering Research Center of Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, ChinaV<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> catalysts with different V<sub>2</sub>O<sub>5</sub> and WO<sub>3</sub> loadings were prepared by the impregnation method. H<sub>2</sub>O and SO<sub>2</sub> resistance of the catalysts under high H<sub>2</sub>O concentration (30 vol.%) was studied. Influence of various basic metal oxides, such as Al<sub>2</sub>O<sub>3</sub>, CaO, Na<sub>2</sub>O, and K<sub>2</sub>O on the catalytic performance was studied and compared. It is revealed that the inhibitory effect is in the sequence of K &gt; Na &gt; Ca &gt; Al, which is consistent with their alkalinity. X-ray diffraction (XRD), N<sub>2</sub> physisorption (BET), temperature-programmed desorption of NH<sub>3</sub> (NH<sub>3</sub>-TPD), H<sub>2</sub>-temperature programmed reduction (H<sub>2</sub>-TPR), X-ray photoelectron spectroscopy (XPS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) were carried out, and the results were well-correlated with the catalytic studies.https://www.mdpi.com/2073-4344/9/3/220selective catalytic reductionV<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub>H<sub>2</sub>O and SO<sub>2</sub> resistancebasic metals
collection DOAJ
language English
format Article
sources DOAJ
author Ruliang Ning
Li Chen
Erwei Li
Xiaolong Liu
Tingyu Zhu
spellingShingle Ruliang Ning
Li Chen
Erwei Li
Xiaolong Liu
Tingyu Zhu
Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
Catalysts
selective catalytic reduction
V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub>
H<sub>2</sub>O and SO<sub>2</sub> resistance
basic metals
author_facet Ruliang Ning
Li Chen
Erwei Li
Xiaolong Liu
Tingyu Zhu
author_sort Ruliang Ning
title Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
title_short Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
title_full Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
title_fullStr Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
title_full_unstemmed Applicability of V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> Catalysts for the SCR Denitrification of Alumina Calcining Flue Gas
title_sort applicability of v<sub>2</sub>o<sub>5</sub>-wo<sub>3</sub>/tio<sub>2</sub> catalysts for the scr denitrification of alumina calcining flue gas
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2019-02-01
description V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub> catalysts with different V<sub>2</sub>O<sub>5</sub> and WO<sub>3</sub> loadings were prepared by the impregnation method. H<sub>2</sub>O and SO<sub>2</sub> resistance of the catalysts under high H<sub>2</sub>O concentration (30 vol.%) was studied. Influence of various basic metal oxides, such as Al<sub>2</sub>O<sub>3</sub>, CaO, Na<sub>2</sub>O, and K<sub>2</sub>O on the catalytic performance was studied and compared. It is revealed that the inhibitory effect is in the sequence of K &gt; Na &gt; Ca &gt; Al, which is consistent with their alkalinity. X-ray diffraction (XRD), N<sub>2</sub> physisorption (BET), temperature-programmed desorption of NH<sub>3</sub> (NH<sub>3</sub>-TPD), H<sub>2</sub>-temperature programmed reduction (H<sub>2</sub>-TPR), X-ray photoelectron spectroscopy (XPS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) were carried out, and the results were well-correlated with the catalytic studies.
topic selective catalytic reduction
V<sub>2</sub>O<sub>5</sub>-WO<sub>3</sub>/TiO<sub>2</sub>
H<sub>2</sub>O and SO<sub>2</sub> resistance
basic metals
url https://www.mdpi.com/2073-4344/9/3/220
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