Microwave-assisted practical and simple method for heterocyclization of o-phenylenediamine and aldehydes using DDQ as oxidant agent
In this research, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been used in the condensation reaction between o-phenylenediamine and various arylaldehydes as oxidants under microwave irradiation. In this clean reaction, the benzimidazole derivatives were synthesized as benefit target products...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis Group
2017-07-01
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| Series: | Green Chemistry Letters and Reviews |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1080/17518253.2017.1314555 |
| Summary: | In this research, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been used in the condensation reaction between o-phenylenediamine and various arylaldehydes as oxidants under microwave irradiation. In this clean reaction, the benzimidazole derivatives were synthesized as benefit target products. The advantages to this procedure include high yields, easy work-up procedure, no chromatographic separation, and short reaction times. The obtained pure products were characterized by physical and spectral data such as IR, 1H NMR and 13C NMR techniques. |
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| ISSN: | 1751-8253 1751-7192 |