Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece
The present paper emphasizes the importance of measuring the oxygen isotopic and chemical compositions of ancient glass, in order to constrain some features such as age, raw materials, and production technologies and to identify the “fingerprint” of local productions. In this context, thirty-nine Ro...
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doaj-ac4f2279d7bd40eb8ea91da0da40898d2020-11-24T22:41:23ZengHindawi LimitedJournal of Chemistry2090-90632090-90712017-01-01201710.1155/2017/29560752956075Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern GreeceAlberta Silvestri0Elissavet Dotsika1Antonio Longinelli2Enricomaria Selmo3Sophia Doukata-Demertzi4Department of Geosciences, University of Padova, Via G. Gradenigo 6, 35131 Padova, ItalyInstitute of Material Science, Stable Isotope Unit, NCSR “Demokritos”, Aghia Paraskevi, 15310 Attiki, GreeceDepartment of Physics and Earth Sciences, University of Parma, Via G.P. Usberti 157A, 43100 Parma, ItalyDepartment of Physics and Earth Sciences, University of Parma, Via G.P. Usberti 157A, 43100 Parma, Italy12th Ephorate of Byzantine Antiquities, General Directorate of Antiquities and Cultural Heritage, Athens, GreeceThe present paper emphasizes the importance of measuring the oxygen isotopic and chemical compositions of ancient glass, in order to constrain some features such as age, raw materials, and production technologies and to identify the “fingerprint” of local productions. In this context, thirty-nine Roman and late Antique glass samples and eight chert samples from northern Greece were selected and analysed for their oxygen isotopic and chemical compositions. Results show that the majority of glass samples are produced using natron as flux and have δ18O values of about 15.5‰, plus or minus a few tenths of one per mil, suggesting that raw materials probably come from Levantine area. Four samples are heavily enriched in 18O, and their chemical composition clearly shows that they were made with soda plant ash as flux. Isotopic and chemical data of Greek chert samples support the hypothesis of local production of the above samples. About half of the glass samples have chemical compositions, which allow their age to be constrained to the late Antique period. For the remaining glass, similarities with literature compositional groups are reported and discussed.http://dx.doi.org/10.1155/2017/2956075 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Alberta Silvestri Elissavet Dotsika Antonio Longinelli Enricomaria Selmo Sophia Doukata-Demertzi |
spellingShingle |
Alberta Silvestri Elissavet Dotsika Antonio Longinelli Enricomaria Selmo Sophia Doukata-Demertzi Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece Journal of Chemistry |
author_facet |
Alberta Silvestri Elissavet Dotsika Antonio Longinelli Enricomaria Selmo Sophia Doukata-Demertzi |
author_sort |
Alberta Silvestri |
title |
Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece |
title_short |
Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece |
title_full |
Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece |
title_fullStr |
Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece |
title_full_unstemmed |
Chemical and Oxygen Isotopic Composition of Roman and Late Antique Glass from Northern Greece |
title_sort |
chemical and oxygen isotopic composition of roman and late antique glass from northern greece |
publisher |
Hindawi Limited |
series |
Journal of Chemistry |
issn |
2090-9063 2090-9071 |
publishDate |
2017-01-01 |
description |
The present paper emphasizes the importance of measuring the oxygen isotopic and chemical compositions of ancient glass, in order to constrain some features such as age, raw materials, and production technologies and to identify the “fingerprint” of local productions. In this context, thirty-nine Roman and late Antique glass samples and eight chert samples from northern Greece were selected and analysed for their oxygen isotopic and chemical compositions. Results show that the majority of glass samples are produced using natron as flux and have δ18O values of about 15.5‰, plus or minus a few tenths of one per mil, suggesting that raw materials probably come from Levantine area. Four samples are heavily enriched in 18O, and their chemical composition clearly shows that they were made with soda plant ash as flux. Isotopic and chemical data of Greek chert samples support the hypothesis of local production of the above samples. About half of the glass samples have chemical compositions, which allow their age to be constrained to the late Antique period. For the remaining glass, similarities with literature compositional groups are reported and discussed. |
url |
http://dx.doi.org/10.1155/2017/2956075 |
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