Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

The SnIV atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of...

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Main Authors: Yaya Sow, Libasse Diop, Kieran C. Molloy, Gabriele Kociok-Köhn
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812043462
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spelling doaj-ac625f20503d445fae3420f5cb6ca5c02020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1436m143610.1107/S1600536812043462Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]Yaya SowLibasse DiopKieran C. MolloyGabriele Kociok-KöhnThe SnIV atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O—H...S and C—H... S hydrogen-bonding interactions into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812043462
collection DOAJ
language English
format Article
sources DOAJ
author Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
spellingShingle Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
Acta Crystallographica Section E
author_facet Yaya Sow
Libasse Diop
Kieran C. Molloy
Gabriele Kociok-Köhn
author_sort Yaya Sow
title Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
title_short Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
title_full Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
title_fullStr Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
title_full_unstemmed Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]
title_sort di-μ-hydroxido-bis[dimethyl(thiocyanato-κn)tin(iv)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The SnIV atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal–bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O—H...S and C—H... S hydrogen-bonding interactions into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812043462
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AT libassediop diamp956hydroxidobisdimethylthiocyanatoamp954ntiniv
AT kierancmolloy diamp956hydroxidobisdimethylthiocyanatoamp954ntiniv
AT gabrielekociokkamp246hn diamp956hydroxidobisdimethylthiocyanatoamp954ntiniv
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