Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The cry...
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International Union of Crystallography
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doaj-ac822f54a2de4c43b18c8ca2c65809152021-06-07T14:20:00ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902021-06-0177665365710.1107/S2056989021005387dj2024Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamideHisakazu Miyamoto0Hiroki Takahashi1Department of Liberal Arts (Sciences & Mathematics), National Institute of Technology, Kurume College, Fukuoka 830-8555, JapanGraduate School of Human and Environmental Studies, Kyoto University, Kyoto 606-8501, JapanThe title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in acetonitrile solution to give racemic 3-(p-phenylphenyl)-3-hydroxy-N-isopropyl-4,4-dimethylazetidin-2-one.http://scripts.iucr.org/cgi-bin/paper?S2056989021005387crystal structurephotoreactionchiral crystal |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hisakazu Miyamoto Hiroki Takahashi |
spellingShingle |
Hisakazu Miyamoto Hiroki Takahashi Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide Acta Crystallographica Section E: Crystallographic Communications crystal structure photoreaction chiral crystal |
author_facet |
Hisakazu Miyamoto Hiroki Takahashi |
author_sort |
Hisakazu Miyamoto |
title |
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide |
title_short |
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide |
title_full |
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide |
title_fullStr |
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide |
title_full_unstemmed |
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide |
title_sort |
crystal structure and photoreactive behaviour of n,n-diisopropyl(p-phenylphenyl)glyoxylamide |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2021-06-01 |
description |
The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in acetonitrile solution to give racemic 3-(p-phenylphenyl)-3-hydroxy-N-isopropyl-4,4-dimethylazetidin-2-one. |
topic |
crystal structure photoreaction chiral crystal |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989021005387 |
work_keys_str_mv |
AT hisakazumiyamoto crystalstructureandphotoreactivebehaviourofnndiisopropylpphenylphenylglyoxylamide AT hirokitakahashi crystalstructureandphotoreactivebehaviourofnndiisopropylpphenylphenylglyoxylamide |
_version_ |
1721391275498799104 |