Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide

Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide

The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The cry...

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Main Authors: Hisakazu Miyamoto, Hiroki Takahashi
Format: Article
Language:English
Published: International Union of Crystallography 2021-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
photoreaction
chiral crystal
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021005387
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spelling doaj-ac822f54a2de4c43b18c8ca2c65809152021-06-07T14:20:00ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902021-06-0177665365710.1107/S2056989021005387dj2024Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamideHisakazu Miyamoto0Hiroki Takahashi1Department of Liberal Arts (Sciences & Mathematics), National Institute of Technology, Kurume College, Fukuoka 830-8555, JapanGraduate School of Human and Environmental Studies, Kyoto University, Kyoto 606-8501, JapanThe title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in acetonitrile solution to give racemic 3-(p-phenylphenyl)-3-hydroxy-N-isopropyl-4,4-dimethylazetidin-2-one.http://scripts.iucr.org/cgi-bin/paper?S2056989021005387crystal structurephotoreactionchiral crystal
collection DOAJ
language English
format Article
sources DOAJ
author Hisakazu Miyamoto
Hiroki Takahashi
spellingShingle Hisakazu Miyamoto
Hiroki Takahashi
Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
photoreaction
chiral crystal
author_facet Hisakazu Miyamoto
Hiroki Takahashi
author_sort Hisakazu Miyamoto
title Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
title_short Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
title_full Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
title_fullStr Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
title_full_unstemmed Crystal structure and photoreactive behaviour of N,N-diisopropyl(p-phenylphenyl)glyoxylamide
title_sort crystal structure and photoreactive behaviour of n,n-diisopropyl(p-phenylphenyl)glyoxylamide
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2021-06-01
description The title compound [systematic name: 2-([1,1′-biphenyl]-4-yl)-2-oxo-N,N-bis(propan-2-yl)acetamide], C20H23NO2 was synthesized and its photoreactive properties in the crystalline state and in acetonitrile solution were investigated. The compound crystallizes in the chiral space group P212121. The crystal does not react under UV light irradiation, perhaps due to the presence of the biphenyl group. However, the compound is photoreactive in acetonitrile solution to give racemic 3-(p-phenylphenyl)-3-hydroxy-N-isopropyl-4,4-dimethylazetidin-2-one.
topic crystal structure
photoreaction
chiral crystal
url http://scripts.iucr.org/cgi-bin/paper?S2056989021005387
work_keys_str_mv AT hisakazumiyamoto crystalstructureandphotoreactivebehaviourofnndiisopropylpphenylphenylglyoxylamide
AT hirokitakahashi crystalstructureandphotoreactivebehaviourofnndiisopropylpphenylphenylglyoxylamide
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