4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate

4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate

The asymmetric unit of the title compound, C16H12Cl4N2O2, comprises half of a potentially tetradentate Schiff base ligand, located about a twofold rotation axis which bisects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterion...

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Main Authors: Reza Kia, Hadi Kargar, Amir Adabi Ardakani, Muhammad Nawaz Tahir
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681202870X
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spelling doaj-ad1adcdc7e4245e9a46db73134a44c272020-11-25T02:00:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2242o224310.1107/S160053681202870X4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolateReza KiaHadi KargarAmir Adabi ArdakaniMuhammad Nawaz TahirThe asymmetric unit of the title compound, C16H12Cl4N2O2, comprises half of a potentially tetradentate Schiff base ligand, located about a twofold rotation axis which bisects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intramolecular N—H...O hydrogen bonds making S(6) ring motifs. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Cl...Cl [3.4395 (9) Å] contacts present.http://scripts.iucr.org/cgi-bin/paper?S160053681202870X
collection DOAJ
language English
format Article
sources DOAJ
author Reza Kia
Hadi Kargar
Amir Adabi Ardakani
Muhammad Nawaz Tahir
spellingShingle Reza Kia
Hadi Kargar
Amir Adabi Ardakani
Muhammad Nawaz Tahir
4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
Acta Crystallographica Section E
author_facet Reza Kia
Hadi Kargar
Amir Adabi Ardakani
Muhammad Nawaz Tahir
author_sort Reza Kia
title 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
title_short 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
title_full 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
title_fullStr 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
title_full_unstemmed 4,6-Dichloro-2-[(E)-(2-{[(E)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
title_sort 4,6-dichloro-2-[(e)-(2-{[(e)-3,5-dichloro-2-oxidobenzylidene]azaniumyl}ethyl)iminiumylmethyl]phenolate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description The asymmetric unit of the title compound, C16H12Cl4N2O2, comprises half of a potentially tetradentate Schiff base ligand, located about a twofold rotation axis which bisects the central C—C bond of the ethane-1,2-diamine group. In the solid state, the compound exists in the zwitterionic form. There are two intramolecular N—H...O hydrogen bonds making S(6) ring motifs. In the crystal, molecules are linked by C—H...O hydrogen bonds, forming two-dimensional frameworks which lie parallel to (100). There are also short Cl...Cl [3.4395 (9) Å] contacts present.
url http://scripts.iucr.org/cgi-bin/paper?S160053681202870X
work_keys_str_mv AT rezakia 46dichloro2e2e35dichloro2oxidobenzylideneazaniumylethyliminiumylmethylphenolate
AT hadikargar 46dichloro2e2e35dichloro2oxidobenzylideneazaniumylethyliminiumylmethylphenolate
AT amiradabiardakani 46dichloro2e2e35dichloro2oxidobenzylideneazaniumylethyliminiumylmethylphenolate
AT muhammadnawaztahir 46dichloro2e2e35dichloro2oxidobenzylideneazaniumylethyliminiumylmethylphenolate
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