Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis
Visible light photocatalytic radical carbonylation has been established as a robust tool for the efficient synthesis of carbonyl-containing compounds. Acyl radicals serve as the key intermediates in these useful transformations and can be generated from the addition of alkyl or aryl radicals to carb...
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doaj-ad221cfe5f184a8ea7b11702518850992020-11-25T03:06:34ZengMDPI AGCatalysts2073-43442020-09-01101054105410.3390/catal10091054Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox CatalysisXiao-Qiang Hu0Zi-Kui Liu1Wen-Jing Xiao2Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, School of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, ChinaKey Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, School of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, ChinaKey Laboratory of Pesticide & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University (CCNU), Wuhan 430079, ChinaVisible light photocatalytic radical carbonylation has been established as a robust tool for the efficient synthesis of carbonyl-containing compounds. Acyl radicals serve as the key intermediates in these useful transformations and can be generated from the addition of alkyl or aryl radicals to carbon monoxide (CO) or various acyl radical precursors such as aldehydes, carboxylic acids, anhydrides, acyl chlorides or α-keto acids. In this review, we aim to summarize the impact of visible light-induced acyl radical carbonylation reactions on the synthesis of oxygen and nitrogen heterocycles. The discussion is mainly categorized based on different types of acyl radical precursors.https://www.mdpi.com/2073-4344/10/9/1054radical carbonylationacyl radicalvisible light photocatalysisheterocycles |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xiao-Qiang Hu Zi-Kui Liu Wen-Jing Xiao |
spellingShingle |
Xiao-Qiang Hu Zi-Kui Liu Wen-Jing Xiao Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis Catalysts radical carbonylation acyl radical visible light photocatalysis heterocycles |
author_facet |
Xiao-Qiang Hu Zi-Kui Liu Wen-Jing Xiao |
author_sort |
Xiao-Qiang Hu |
title |
Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis |
title_short |
Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis |
title_full |
Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis |
title_fullStr |
Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis |
title_full_unstemmed |
Radical Carbonylative Synthesis of Heterocycles by Visible Light Photoredox Catalysis |
title_sort |
radical carbonylative synthesis of heterocycles by visible light photoredox catalysis |
publisher |
MDPI AG |
series |
Catalysts |
issn |
2073-4344 |
publishDate |
2020-09-01 |
description |
Visible light photocatalytic radical carbonylation has been established as a robust tool for the efficient synthesis of carbonyl-containing compounds. Acyl radicals serve as the key intermediates in these useful transformations and can be generated from the addition of alkyl or aryl radicals to carbon monoxide (CO) or various acyl radical precursors such as aldehydes, carboxylic acids, anhydrides, acyl chlorides or α-keto acids. In this review, we aim to summarize the impact of visible light-induced acyl radical carbonylation reactions on the synthesis of oxygen and nitrogen heterocycles. The discussion is mainly categorized based on different types of acyl radical precursors. |
topic |
radical carbonylation acyl radical visible light photocatalysis heterocycles |
url |
https://www.mdpi.com/2073-4344/10/9/1054 |
work_keys_str_mv |
AT xiaoqianghu radicalcarbonylativesynthesisofheterocyclesbyvisiblelightphotoredoxcatalysis AT zikuiliu radicalcarbonylativesynthesisofheterocyclesbyvisiblelightphotoredoxcatalysis AT wenjingxiao radicalcarbonylativesynthesisofheterocyclesbyvisiblelightphotoredoxcatalysis |
_version_ |
1724673557161574400 |