Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles
The present work focuses on the synthesis and application of imine-modified silica-coated magnetic (IM-SCM) nanoparticles. The X-ray diffraction (XRD) tests indicated the presence of highly crystalline cubic spinel magnetite both before and after coating with the silica. The FTIR spectra also proved...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Iranian Research Organization for Science and Technology (IROST)
2018-10-01
|
Series: | Advances in Environmental Technology |
Subjects: | |
Online Access: | http://aet.irost.ir/article_839_aa159af08fbc030684fd56e54f325ea6.pdf |
id |
doaj-aeddd5385c664e0f9378ccbc28729d3d |
---|---|
record_format |
Article |
spelling |
doaj-aeddd5385c664e0f9378ccbc28729d3d2020-11-25T02:59:30ZengIranian Research Organization for Science and Technology (IROST) Advances in Environmental Technology2476-66742476-47792018-10-014422323110.22104/aet.2019.3324.1164839Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticlesHadis Shooshtary0Leila Hajiaghababaei1Alireza Badiei2Mohammad Reza Ganjali3Ghodsi Mohammadi Ziarani4Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, IranDepartment of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre-rey Branch, Islamic Azad University, Tehran, IranSchool of Chemistry, College of Science, University of Tehran, Tehran, IranCenter of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, IranDepartment of Chemistry, Alzahra University, Tehran, IranThe present work focuses on the synthesis and application of imine-modified silica-coated magnetic (IM-SCM) nanoparticles. The X-ray diffraction (XRD) tests indicated the presence of highly crystalline cubic spinel magnetite both before and after coating with the silica. The FTIR spectra also proved the successful surface coating and imine-modification of the Fe<sub>3</sub>O<sub>4</sub> nanoparticles. Further investigations were performed to examine the capability of the modified IM-SCM nanoparticles for simultaneous removal of Ag<sup>+</sup> and Cu<sup>2+ </sup>from the water samples. Atomic absorption spectrometry was used for ion determination. The best operating conditions for removing the target ions were a pH=5-9 and a stirring time=30 min. Only 20 mL of 3M nitric acid was used for stripping the ions using the IM-SCM nanoparticles. The resulting data were found to fit well with the Langmuir model, and the maximum capacity of the adsorbent was determined to be 270.3 (± 1.4) mg and 256.4 (± 0.9) mg of Ag<sup>+</sup> and Cu<sup>2+ </sup>/g of IM-SCM, respectively. The adsorbent was successfully used for simultaneously removing the target ions from the wastewater samples.http://aet.irost.ir/article_839_aa159af08fbc030684fd56e54f325ea6.pdfag+cu2+imine-modified silica-coated magnetic nanoparticlesremovalwastewater |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Hadis Shooshtary Leila Hajiaghababaei Alireza Badiei Mohammad Reza Ganjali Ghodsi Mohammadi Ziarani |
spellingShingle |
Hadis Shooshtary Leila Hajiaghababaei Alireza Badiei Mohammad Reza Ganjali Ghodsi Mohammadi Ziarani Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles Advances in Environmental Technology ag+ cu2+ imine-modified silica-coated magnetic nanoparticles removal wastewater |
author_facet |
Hadis Shooshtary Leila Hajiaghababaei Alireza Badiei Mohammad Reza Ganjali Ghodsi Mohammadi Ziarani |
author_sort |
Hadis Shooshtary |
title |
Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
title_short |
Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
title_full |
Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
title_fullStr |
Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
title_full_unstemmed |
Efficient removal of Ag+ and Cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
title_sort |
efficient removal of ag+ and cu2+ using imine-modified/mesoporous silica-coated magnetic nanoparticles |
publisher |
Iranian Research Organization for Science and Technology (IROST) |
series |
Advances in Environmental Technology |
issn |
2476-6674 2476-4779 |
publishDate |
2018-10-01 |
description |
The present work focuses on the synthesis and application of imine-modified silica-coated magnetic (IM-SCM) nanoparticles. The X-ray diffraction (XRD) tests indicated the presence of highly crystalline cubic spinel magnetite both before and after coating with the silica. The FTIR spectra also proved the successful surface coating and imine-modification of the Fe<sub>3</sub>O<sub>4</sub> nanoparticles. Further investigations were performed to examine the capability of the modified IM-SCM nanoparticles for simultaneous removal of Ag<sup>+</sup> and Cu<sup>2+ </sup>from the water samples. Atomic absorption spectrometry was used for ion determination. The best operating conditions for removing the target ions were a pH=5-9 and a stirring time=30 min. Only 20 mL of 3M nitric acid was used for stripping the ions using the IM-SCM nanoparticles. The resulting data were found to fit well with the Langmuir model, and the maximum capacity of the adsorbent was determined to be 270.3 (± 1.4) mg and 256.4 (± 0.9) mg of Ag<sup>+</sup> and Cu<sup>2+ </sup>/g of IM-SCM, respectively. The adsorbent was successfully used for simultaneously removing the target ions from the wastewater samples. |
topic |
ag+ cu2+ imine-modified silica-coated magnetic nanoparticles removal wastewater |
url |
http://aet.irost.ir/article_839_aa159af08fbc030684fd56e54f325ea6.pdf |
work_keys_str_mv |
AT hadisshooshtary efficientremovalofagandcu2usingiminemodifiedmesoporoussilicacoatedmagneticnanoparticles AT leilahajiaghababaei efficientremovalofagandcu2usingiminemodifiedmesoporoussilicacoatedmagneticnanoparticles AT alirezabadiei efficientremovalofagandcu2usingiminemodifiedmesoporoussilicacoatedmagneticnanoparticles AT mohammadrezaganjali efficientremovalofagandcu2usingiminemodifiedmesoporoussilicacoatedmagneticnanoparticles AT ghodsimohammadiziarani efficientremovalofagandcu2usingiminemodifiedmesoporoussilicacoatedmagneticnanoparticles |
_version_ |
1724701977920667648 |