2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione

2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione

The crystal structure of the title compound, C9H12O4S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located...

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Main Authors: Savvas Ioannou, Eleni Moushi
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681202079X
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spelling doaj-aef4f567124040fea2589b86dc8b907b2020-11-25T01:10:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1719o171910.1107/S160053681202079X2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dioneSavvas IoannouEleni MoushiThe crystal structure of the title compound, C9H12O4S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C—C bonds of the molecule due to the stretch of the cage structure. http://scripts.iucr.org/cgi-bin/paper?S160053681202079X
collection DOAJ
language English
format Article
sources DOAJ
author Savvas Ioannou
Eleni Moushi
spellingShingle Savvas Ioannou
Eleni Moushi
2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
Acta Crystallographica Section E
author_facet Savvas Ioannou
Eleni Moushi
author_sort Savvas Ioannou
title 2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
title_short 2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
title_full 2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
title_fullStr 2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
title_full_unstemmed 2,4-Dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
title_sort 2,4-dioxa-λ6-thiatetracyclo[5.3.1.15,9.01,5]dodecane-3,3-dione
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The crystal structure of the title compound, C9H12O4S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C—C bonds of the molecule due to the stretch of the cage structure.
url http://scripts.iucr.org/cgi-bin/paper?S160053681202079X
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AT elenimoushi 24dioxaamp9556thiatetracyclo531159015dodecane33dione
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