Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
In the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antipr...
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International Union of Crystallography
2012-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811054961 |
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doaj-af1a649da3e54c89882d93591296dc812020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m96m9610.1107/S1600536811054961Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvateSadegh SalehzadehMahsa MahdavianMehdi KhalajIn the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811054961 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Sadegh Salehzadeh Mahsa Mahdavian Mehdi Khalaj |
spellingShingle |
Sadegh Salehzadeh Mahsa Mahdavian Mehdi Khalaj Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate Acta Crystallographica Section E |
author_facet |
Sadegh Salehzadeh Mahsa Mahdavian Mehdi Khalaj |
author_sort |
Sadegh Salehzadeh |
title |
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_short |
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_full |
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_fullStr |
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_full_unstemmed |
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_sort |
aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(iii) acetonitrile monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-02-01 |
description |
In the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H...O hydrogen bonds. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811054961 |
work_keys_str_mv |
AT sadeghsalehzadeh aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate AT mahsamahdavian aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate AT mehdikhalaj aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate |
_version_ |
1724896599632510976 |