Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate

In the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antipr...

Full description

Bibliographic Details
Main Authors: Sadegh Salehzadeh, Mahsa Mahdavian, Mehdi Khalaj
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811054961
id doaj-af1a649da3e54c89882d93591296dc81
record_format Article
spelling doaj-af1a649da3e54c89882d93591296dc812020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m96m9610.1107/S1600536811054961Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvateSadegh SalehzadehMahsa MahdavianMehdi KhalajIn the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811054961
collection DOAJ
language English
format Article
sources DOAJ
author Sadegh Salehzadeh
Mahsa Mahdavian
Mehdi Khalaj
spellingShingle Sadegh Salehzadeh
Mahsa Mahdavian
Mehdi Khalaj
Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
Acta Crystallographica Section E
author_facet Sadegh Salehzadeh
Mahsa Mahdavian
Mehdi Khalaj
author_sort Sadegh Salehzadeh
title Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
title_short Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
title_full Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
title_fullStr Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
title_full_unstemmed Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
title_sort aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(iii) acetonitrile monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description In the title compound, [Sm(C48H45N10O3)(H2O)]·CH3CN, the SmIII ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN4O4 coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811054961
work_keys_str_mv AT sadeghsalehzadeh aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate
AT mahsamahdavian aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate
AT mehdikhalaj aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate
_version_ 1724896599632510976