Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate

In the title compound, [Mn(C7H7N2O4)2(H2O)2]·2C3H7NO, the central MnII ion, located on an inversion center, is hexacoordinated by four O atoms from two water molecules and two carboxylate groups, and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anions in a slightly...

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Main Authors: Gang Zhang, Yong Wang
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811020071
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spelling doaj-af1ee36fc21a4eadb0b23cf93cf047102020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m828m82810.1107/S1600536811020071Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvateGang ZhangYong WangIn the title compound, [Mn(C7H7N2O4)2(H2O)2]·2C3H7NO, the central MnII ion, located on an inversion center, is hexacoordinated by four O atoms from two water molecules and two carboxylate groups, and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anions in a slightly distorted octahedral environment. The complex molecules and solvent molecules are connected via N—H...O and O—H...O hydrogen bonds into a two-dimensional polymeric structure parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S1600536811020071
collection DOAJ
language English
format Article
sources DOAJ
author Gang Zhang
Yong Wang
spellingShingle Gang Zhang
Yong Wang
Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
Acta Crystallographica Section E
author_facet Gang Zhang
Yong Wang
author_sort Gang Zhang
title Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
title_short Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
title_full Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
title_fullStr Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
title_full_unstemmed Diaquabis(4-carboxy-2-ethyl-1H-imidazole-5-carboxylato-κ2N3,O4)manganese(II) N,N-dimethylformamide disolvate
title_sort diaquabis(4-carboxy-2-ethyl-1h-imidazole-5-carboxylato-κ2n3,o4)manganese(ii) n,n-dimethylformamide disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the title compound, [Mn(C7H7N2O4)2(H2O)2]·2C3H7NO, the central MnII ion, located on an inversion center, is hexacoordinated by four O atoms from two water molecules and two carboxylate groups, and two N atoms from two 4-carboxy-2-ethyl-1H-imidazole-5-carboxylate anions in a slightly distorted octahedral environment. The complex molecules and solvent molecules are connected via N—H...O and O—H...O hydrogen bonds into a two-dimensional polymeric structure parallel to (001).
url http://scripts.iucr.org/cgi-bin/paper?S1600536811020071
work_keys_str_mv AT gangzhang diaquabis4carboxy2ethyl1himidazole5carboxylatoamp9542n3o4manganeseiinndimethylformamidedisolvate
AT yongwang diaquabis4carboxy2ethyl1himidazole5carboxylatoamp9542n3o4manganeseiinndimethylformamidedisolvate
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