Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)

Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)

A new mononuclear NiII complex with bis(pyridin-2-yl)amine (dpyam) and benzoate (benz), [Ni(C7H5O2)2(C10H9N3)], crystallizes in the monoclinic space group P21/c. The NiII ion adopts a cis-distorted octahedral geometry with an [NiN2O4] chromophore. In the crystal, the complex molecules are linked tog...

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Main Authors: Phichitra Phiokliang, Phakamat Promwit, Kittipong Chainok, Nanthawat Wannarit
Format: Article
Language:English
Published: International Union of Crystallography 2019-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
nickel(II) complex
benzoate
bis(pyridin-2-yl)amine
crystal structure
Hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019010880
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spelling doaj-af306cbdb4e242f2b25522233157ec162020-11-25T02:23:44ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-09-017591301130510.1107/S2056989019010880zl2759Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)Phichitra Phiokliang0Phakamat Promwit1Kittipong Chainok2Nanthawat Wannarit3Department of Chemistry, Faculty of Science and Technology, Thammasat, University, Klong Luang, Pathum Thani 12121, ThailandDepartment of Chemistry, Faculty of Science and Technology, Thammasat, University, Klong Luang, Pathum Thani 12121, ThailandMaterials and Textile Technology, Faculty of Science and Technology, Thammasat University, Klong Luang, Pathum Thani 12121, ThailandDepartment of Chemistry, Faculty of Science and Technology, Thammasat, University, Klong Luang, Pathum Thani 12121, ThailandA new mononuclear NiII complex with bis(pyridin-2-yl)amine (dpyam) and benzoate (benz), [Ni(C7H5O2)2(C10H9N3)], crystallizes in the monoclinic space group P21/c. The NiII ion adopts a cis-distorted octahedral geometry with an [NiN2O4] chromophore. In the crystal, the complex molecules are linked together into a one-dimensional chain by symmetry-related π–π stacking interactions [centroid-to-centroid distance = 3.7257 (17) Å], along with N—H...O and C—H...O hydrogen bonds. The crystal packing is further stabilized by C—H...π interactions, which were investigated by Hirshfeld surface analysis.http://scripts.iucr.org/cgi-bin/paper?S2056989019010880nickel(II) complexbenzoatebis(pyridin-2-yl)aminecrystal structureHirshfeld surface analysis
collection DOAJ
language English
format Article
sources DOAJ
author Phichitra Phiokliang
Phakamat Promwit
Kittipong Chainok
Nanthawat Wannarit
spellingShingle Phichitra Phiokliang
Phakamat Promwit
Kittipong Chainok
Nanthawat Wannarit
Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
Acta Crystallographica Section E: Crystallographic Communications
nickel(II) complex
benzoate
bis(pyridin-2-yl)amine
crystal structure
Hirshfeld surface analysis
author_facet Phichitra Phiokliang
Phakamat Promwit
Kittipong Chainok
Nanthawat Wannarit
author_sort Phichitra Phiokliang
title Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
title_short Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
title_full Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of bis(benzoato-κ2O,O′)[bis(pyridin-2-yl-κN)amine]nickel(II)
title_sort crystal structure and hirshfeld surface analysis of bis(benzoato-κ2o,o′)[bis(pyridin-2-yl-κn)amine]nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2019-09-01
description A new mononuclear NiII complex with bis(pyridin-2-yl)amine (dpyam) and benzoate (benz), [Ni(C7H5O2)2(C10H9N3)], crystallizes in the monoclinic space group P21/c. The NiII ion adopts a cis-distorted octahedral geometry with an [NiN2O4] chromophore. In the crystal, the complex molecules are linked together into a one-dimensional chain by symmetry-related π–π stacking interactions [centroid-to-centroid distance = 3.7257 (17) Å], along with N—H...O and C—H...O hydrogen bonds. The crystal packing is further stabilized by C—H...π interactions, which were investigated by Hirshfeld surface analysis.
topic nickel(II) complex
benzoate
bis(pyridin-2-yl)amine
crystal structure
Hirshfeld surface analysis
url http://scripts.iucr.org/cgi-bin/paper?S2056989019010880
work_keys_str_mv AT phichitraphiokliang crystalstructureandhirshfeldsurfaceanalysisofbisbenzoatok2oobispyridin2ylknaminenickelii
AT phakamatpromwit crystalstructureandhirshfeldsurfaceanalysisofbisbenzoatok2oobispyridin2ylknaminenickelii
AT kittipongchainok crystalstructureandhirshfeldsurfaceanalysisofbisbenzoatok2oobispyridin2ylknaminenickelii
AT nanthawatwannarit crystalstructureandhirshfeldsurfaceanalysisofbisbenzoatok2oobispyridin2ylknaminenickelii
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