Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)

Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)

The asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion...

Full description

Bibliographic Details
Main Authors: Johan A. Venter, Hendrik G. Visser, Kina van der Merwe
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811035355
id doaj-b089fca339464733ad8228dbc09ee5d1
record_format Article
spelling doaj-b089fca339464733ad8228dbc09ee5d12020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1354m135410.1107/S1600536811035355Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)Johan A. VenterHendrik G. VisserKina van der MerweThe asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811035355
collection DOAJ
language English
format Article
sources DOAJ
author Johan A. Venter
Hendrik G. Visser
Kina van der Merwe
spellingShingle Johan A. Venter
Hendrik G. Visser
Kina van der Merwe
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
Acta Crystallographica Section E
author_facet Johan A. Venter
Hendrik G. Visser
Kina van der Merwe
author_sort Johan A. Venter
title Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_short Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_full Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_fullStr Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_full_unstemmed Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_sort dicaesium diaquabis(methylenediphosphonato-κ2o,o′)cobaltate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description The asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811035355
work_keys_str_mv AT johanaventer dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii
AT hendrikgvisser dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii
AT kinavandermerwe dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii
_version_ 1725873676528648192

Similar Items