Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
The asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-10-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811035355 |
id |
doaj-b089fca339464733ad8228dbc09ee5d1 |
---|---|
record_format |
Article |
spelling |
doaj-b089fca339464733ad8228dbc09ee5d12020-11-24T21:52:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1354m135410.1107/S1600536811035355Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)Johan A. VenterHendrik G. VisserKina van der MerweThe asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811035355 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Johan A. Venter Hendrik G. Visser Kina van der Merwe |
spellingShingle |
Johan A. Venter Hendrik G. Visser Kina van der Merwe Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) Acta Crystallographica Section E |
author_facet |
Johan A. Venter Hendrik G. Visser Kina van der Merwe |
author_sort |
Johan A. Venter |
title |
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
title_short |
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
title_full |
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
title_fullStr |
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
title_full_unstemmed |
Dicaesium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II) |
title_sort |
dicaesium diaquabis(methylenediphosphonato-κ2o,o′)cobaltate(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-10-01 |
description |
The asymmetric unit of the title compound, Cs2[Co(CH4O6P2)2(H2O)2], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the CoII atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H...O hydrogen bonds. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811035355 |
work_keys_str_mv |
AT johanaventer dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii AT hendrikgvisser dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii AT kinavandermerwe dicaesiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii |
_version_ |
1725873676528648192 |