Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones

Functional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibit...

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Main Authors:	LIU Ketang, XU Yuanyan, DUAN Mengyuan, WEI Fenying, CHEN Qianyun, CHENG Tanyu, LIU Guohua
Format:	Article
Language:	English
Published:	Academic Journals Center of Shanghai Normal University 2013-02-01
Series:	Journal of Shanghai Normal University (Natural Sciences)
Subjects:	graphite oxide immobilization asymmetric transfer hydrogenation rhodium
Online Access:	http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1

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record_format	Article
spelling	doaj-b15bd93ade29423fa8f4ce0114d6f4822020-11-24T21:02:07ZengAcademic Journals Center of Shanghai Normal UniversityJournal of Shanghai Normal University (Natural Sciences)1000-51371000-51372013-02-01421106110201301016Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketonesLIU Ketang0XU Yuanyan1DUAN Mengyuan2WEI Fenying3CHEN Qianyun4CHENG Tanyu5LIU Guohua6College of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityFunctional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibited high catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium under mild condition.http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1graphite oxideimmobilizationasymmetric transfer hydrogenationrhodium
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua
spellingShingle	LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones Journal of Shanghai Normal University (Natural Sciences) graphite oxide immobilization asymmetric transfer hydrogenation rhodium
author_facet	LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua
author_sort	LIU Ketang
title	Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
title_short	Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
title_full	Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
title_fullStr	Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
title_full_unstemmed	Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
title_sort	graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
publisher	Academic Journals Center of Shanghai Normal University
series	Journal of Shanghai Normal University (Natural Sciences)
issn	1000-5137 1000-5137
publishDate	2013-02-01
description	Functional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibited high catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium under mild condition.
topic	graphite oxide immobilization asymmetric transfer hydrogenation rhodium
url	http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1
work_keys_str_mv	AT liuketang grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT xuyuanyan grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT duanmengyuan grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT weifenying grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT chenqianyun grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT chengtanyu grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT liuguohua grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones
_version_	1716776491466883072

Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones

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