Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones
Functional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibit...
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Academic Journals Center of Shanghai Normal University
2013-02-01
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Series: | Journal of Shanghai Normal University (Natural Sciences) |
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Online Access: | http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1 |
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doaj-b15bd93ade29423fa8f4ce0114d6f4822020-11-24T21:02:07ZengAcademic Journals Center of Shanghai Normal UniversityJournal of Shanghai Normal University (Natural Sciences)1000-51371000-51372013-02-01421106110201301016Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketonesLIU Ketang0XU Yuanyan1DUAN Mengyuan2WEI Fenying3CHEN Qianyun4CHENG Tanyu5LIU Guohua6College of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityCollege of Life and Environment Sciences, Shanghai Normal UniversityFunctional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibited high catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium under mild condition.http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1graphite oxideimmobilizationasymmetric transfer hydrogenationrhodium |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua |
spellingShingle |
LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones Journal of Shanghai Normal University (Natural Sciences) graphite oxide immobilization asymmetric transfer hydrogenation rhodium |
author_facet |
LIU Ketang XU Yuanyan DUAN Mengyuan WEI Fenying CHEN Qianyun CHENG Tanyu LIU Guohua |
author_sort |
LIU Ketang |
title |
Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
title_short |
Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
title_full |
Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
title_fullStr |
Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
title_full_unstemmed |
Graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
title_sort |
graphene oxide based chiral diamine rhodium catalyst for asymmetric transfer hydrogenation of aromatic ketones |
publisher |
Academic Journals Center of Shanghai Normal University |
series |
Journal of Shanghai Normal University (Natural Sciences) |
issn |
1000-5137 1000-5137 |
publishDate |
2013-02-01 |
description |
Functional graphite oxide materials were synthesized through the Hummers chemical oxidation of graphite.Heterogeneous catalyst was prepared via direct grafting diamine-based chiral ligand to graphite oxide followed by the complexation with organorhodium complex.Such a chiral rhodium catalyst exhibited high catalytic activity and enantioselectivity in asymmetric transfer hydrogenation of aromatic ketones in aqueous medium under mild condition. |
topic |
graphite oxide immobilization asymmetric transfer hydrogenation rhodium |
url |
http://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/create_pdf.aspx?file_no=201301016&year_id=2013&quarter_id=1&falg=1 |
work_keys_str_mv |
AT liuketang grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT xuyuanyan grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT duanmengyuan grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT weifenying grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT chenqianyun grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT chengtanyu grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones AT liuguohua grapheneoxidebasedchiraldiaminerhodiumcatalystforasymmetrictransferhydrogenationofaromaticketones |
_version_ |
1716776491466883072 |