(E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide

(E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide

The molecule of the title benzohydrazide derivative, C15H14N2O4, is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the methoxy group deviates slightly [C&#...

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Main Authors: Premrudee Promdet, Jirapa Horkaew, Suchada Chantrapromma, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811045740
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spelling doaj-b1f6b28a3b1b4a73a166e68663367cee2020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3224o322410.1107/S1600536811045740(E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazidePremrudee PromdetJirapa HorkaewSuchada ChantraprommaHoong-Kun FunThe molecule of the title benzohydrazide derivative, C15H14N2O4, is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the methoxy group deviates slightly [C—O—C—C = −10.4 (3)°] from its attached benzene ring. An intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by N—H...O and bifurcated N—H...(O,O) hydrogen bonds, as well as weak C—H...O interactions, into two-dimensional networks lying parallel to the bc plane. A weak C—H...π interaction also occurs.http://scripts.iucr.org/cgi-bin/paper?S1600536811045740
collection DOAJ
language English
format Article
sources DOAJ
author Premrudee Promdet
Jirapa Horkaew
Suchada Chantrapromma
Hoong-Kun Fun
spellingShingle Premrudee Promdet
Jirapa Horkaew
Suchada Chantrapromma
Hoong-Kun Fun
(E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
Acta Crystallographica Section E
author_facet Premrudee Promdet
Jirapa Horkaew
Suchada Chantrapromma
Hoong-Kun Fun
author_sort Premrudee Promdet
title (E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
title_short (E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
title_full (E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
title_fullStr (E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
title_full_unstemmed (E)-N′-(2,3-Dihydroxybenzylidene)-4-methoxybenzohydrazide
title_sort (e)-n′-(2,3-dihydroxybenzylidene)-4-methoxybenzohydrazide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description The molecule of the title benzohydrazide derivative, C15H14N2O4, is twisted and exists in a trans conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 56.86 (9)° and the C atom of the methoxy group deviates slightly [C—O—C—C = −10.4 (3)°] from its attached benzene ring. An intramolecular O—H...N hydrogen bond generates an S(6) ring. In the crystal, molecules are linked by N—H...O and bifurcated N—H...(O,O) hydrogen bonds, as well as weak C—H...O interactions, into two-dimensional networks lying parallel to the bc plane. A weak C—H...π interaction also occurs.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811045740
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AT jirapahorkaew enamp824223dihydroxybenzylidene4methoxybenzohydrazide
AT suchadachantrapromma enamp824223dihydroxybenzylidene4methoxybenzohydrazide
AT hoongkunfun enamp824223dihydroxybenzylidene4methoxybenzohydrazide
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