Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate

Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate

The structure of the title compound, [Co2(C19H11F2O2)4(C5H5N)2(H2O)2]·2C4H10O, comprises two CoII atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co...Co separation of 3.1923 (15) &...

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Main Authors: Namseok Kim, Yeahsel Yoon, Ha-Jin Lee, Sungho Yoon
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812038391
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spelling doaj-b3fe65f13434467d9a01afadb0f043d02020-11-25T01:13:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1264m126510.1107/S1600536812038391Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvateNamseok KimYeahsel YoonHa-Jin LeeSungho YoonThe structure of the title compound, [Co2(C19H11F2O2)4(C5H5N)2(H2O)2]·2C4H10O, comprises two CoII atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co...Co separation of 3.1923 (15) Å. Each Co2+ cation is coordinated by three O atoms of three 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands, one water O atom and one pyridine N atom, forming a CoO4N polyhedron. Strong intramolecular O—H...O hydrogen bonds are observed between terminal metal-bound carboxylate groups and water O atoms.http://scripts.iucr.org/cgi-bin/paper?S1600536812038391
collection DOAJ
language English
format Article
sources DOAJ
author Namseok Kim
Yeahsel Yoon
Ha-Jin Lee
Sungho Yoon
spellingShingle Namseok Kim
Yeahsel Yoon
Ha-Jin Lee
Sungho Yoon
Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
Acta Crystallographica Section E
author_facet Namseok Kim
Yeahsel Yoon
Ha-Jin Lee
Sungho Yoon
author_sort Namseok Kim
title Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_short Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_full Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_fullStr Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_full_unstemmed Bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2O:O′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κO)(pyridine-κN)cobalt(II)] diethyl ether disolvate
title_sort bis(μ-4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κ2o:o′)bis[aqua(4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylato-κo)(pyridine-κn)cobalt(ii)] diethyl ether disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description The structure of the title compound, [Co2(C19H11F2O2)4(C5H5N)2(H2O)2]·2C4H10O, comprises two CoII atoms in a distorted square pyramidal coordination environment, straddling a crystallographic inversion center with a Co...Co separation of 3.1923 (15) Å. Each Co2+ cation is coordinated by three O atoms of three 4,4′′-difluoro-1,1′:3′,1′′-terphenyl-2′-carboxylate ligands, one water O atom and one pyridine N atom, forming a CoO4N polyhedron. Strong intramolecular O—H...O hydrogen bonds are observed between terminal metal-bound carboxylate groups and water O atoms.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812038391
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AT yeahselyoon bisamp95644amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp9542ooamp8242bisaqua44amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp954opyridineamp954ncobaltiidiethyletherdisolvate
AT hajinlee bisamp95644amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp9542ooamp8242bisaqua44amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp954opyridineamp954ncobaltiidiethyletherdisolvate
AT sunghoyoon bisamp95644amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp9542ooamp8242bisaqua44amp8242amp8242difluoro11amp82423amp82421amp8242amp8242terphenyl2amp8242carboxylatoamp954opyridineamp954ncobaltiidiethyletherdisolvate
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