Synthesis, Crystal Structure and Antimicrobial Properties of 1-Diphenylmethylpiperazine-1,4-Diium Tetrachloridocuprate

Synthesis, Crystal Structure and Antimicrobial Properties of 1-Diphenylmethylpiperazine-1,4-Diium Tetrachloridocuprate

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New organic/inorganic hybrid (C17H22N2)[CuCl4] was elaborated and studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic Pbca space group. The isolated [CuCl4]2- tetrahedra are slightly distorted building a 0-D anionic framework. The double protonation of the org...

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Bibliographic Details
Main Authors: Sonia Mokaddem, Hadda-Imene Ouzari, Nedra Korbi, Habib Boughzala
Format: Article
Language:English
Published: PURKH 2018-12-01
Series:To Chemistry Journal
Subjects:
Crystal structure
DRX
copper
1-diphenylmethylpiperazine
hybrid material
infrared spectroscopy
Online Access:https://www.purkh.com/index.php/tochem/article/view/181
Description
Summary:New organic/inorganic hybrid (C17H22N2)[CuCl4] was elaborated and studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic Pbca space group. The isolated [CuCl4]2- tetrahedra are slightly distorted building a 0-D anionic framework. The double protonation of the organic cation establish N—H···Cl interactions between organic and inorganic moieties leading to self-organized structure. Infrared, UV-Visible and photoluminescence studies were carried out. The in-vitro antibacterial and antifungal activity of the title salt against several microorganisms were studied. The purity of the material was controlled by Rietveld analysis based on structural investigations and X-ray powder diffraction.
ISSN:2581-7507

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