Synthesis, Crystal Structure and Antimicrobial Properties of 1-Diphenylmethylpiperazine-1,4-Diium Tetrachloridocuprate
New organic/inorganic hybrid (C17H22N2)[CuCl4] was elaborated and studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic Pbca space group. The isolated [CuCl4]2- tetrahedra are slightly distorted building a 0-D anionic framework. The double protonation of the org...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
PURKH
2018-12-01
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Series: | To Chemistry Journal |
Subjects: | |
Online Access: | https://www.purkh.com/index.php/tochem/article/view/181 |
Summary: | New organic/inorganic hybrid (C17H22N2)[CuCl4] was elaborated and studied by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic Pbca space group. The isolated [CuCl4]2- tetrahedra are slightly distorted building a 0-D anionic framework. The double protonation of the organic cation establish N—H···Cl interactions between organic and inorganic moieties leading to self-organized structure. Infrared, UV-Visible and photoluminescence studies were carried out. The in-vitro antibacterial and antifungal activity of the title salt against several microorganisms were studied. The purity of the material was controlled by Rietveld analysis based on structural investigations and X-ray powder diffraction.
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ISSN: | 2581-7507 |