Summary: | Understanding the cracking behavior during carbonation is of high importance, and the cracks can serve as a shortcut for CO<sub>2</sub> diffusion, which can further accelerate the carbonation process itself. In this study, a sliced paste sample was taken for an accelerated carbonation test, and the cracking behavior, as well as its impact on carbonation, was investigated through a novel extended attenuation method based on X-ray (XRAM) which is performed primarily on computed tomography (CT). Surface-opening cracks at different carbonation ages were rendered, based on which a full view on the carbonation-cracking behavior was built. The results reveal that the crack paths can rapidly be occupied by CO<sub>2</sub>, and that leads to the generation of V-shaped carbonation cusps pervading the carbonation fronts. The V-shaped carbonation cusps were mostly generated at the early carbonation age (within 14 days), attesting to a less intact sample surface as compared to the inside area. Moreover, this study confirms that the carbonated area would split into two independent zones with variant carbonation degree due to the increased humidity level near the sample surface. The current work reveals the interconnection between carbonation and cracking, and the results can be used for the designing of cement-based materials with better carbonation and cracking resistance.
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