catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]

catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]

In the title coordination polymer, [Cu2I2(C14H14N4)(C18H15P)2]n, the CuI atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetrahedral arrangement. A crystallographic inversion centre generates a Cu2I2 diamond with a Cu–Cu separation of 3.0120&#8...

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Main Authors: Anindita Mukherjee, Goutam K. Patra, Wan-Sin Loh, Hoong-Kun Fun, Pankaj K. Pal
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811036555
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spelling doaj-b556b4931b7f48758bff3e2bc9dea8112020-11-25T02:11:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1389m138910.1107/S1600536811036555catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]Anindita MukherjeeGoutam K. PatraWan-Sin LohHoong-Kun FunPankaj K. PalIn the title coordination polymer, [Cu2I2(C14H14N4)(C18H15P)2]n, the CuI atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetrahedral arrangement. A crystallographic inversion centre generates a Cu2I2 diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete N,N′-(1-pyridin-4-yl-ethethylidene)-hydrazine molecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811036555
collection DOAJ
language English
format Article
sources DOAJ
author Anindita Mukherjee
Goutam K. Patra
Wan-Sin Loh
Hoong-Kun Fun
Pankaj K. Pal
spellingShingle Anindita Mukherjee
Goutam K. Patra
Wan-Sin Loh
Hoong-Kun Fun
Pankaj K. Pal
catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
Acta Crystallographica Section E
author_facet Anindita Mukherjee
Goutam K. Patra
Wan-Sin Loh
Hoong-Kun Fun
Pankaj K. Pal
author_sort Anindita Mukherjee
title catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
title_short catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
title_full catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
title_fullStr catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
title_full_unstemmed catena-Poly[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
title_sort catena-poly[[(triphenylphosphane)copper(i)]-di-μ-iodido-[(triphenylphosphane)copper(i)]-μ-{1,2-bis[1-(pyridin-4-yl)ethylidene]hydrazine}]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description In the title coordination polymer, [Cu2I2(C14H14N4)(C18H15P)2]n, the CuI atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetrahedral arrangement. A crystallographic inversion centre generates a Cu2I2 diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete N,N′-(1-pyridin-4-yl-ethethylidene)-hydrazine molecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811036555
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AT wansinloh catenapolytriphenylphosphanecopperidiamp956iodidotriphenylphosphanecopperiamp95612bis1pyridin4ylethylidenehydrazine
AT hoongkunfun catenapolytriphenylphosphanecopperidiamp956iodidotriphenylphosphanecopperiamp95612bis1pyridin4ylethylidenehydrazine
AT pankajkpal catenapolytriphenylphosphanecopperidiamp956iodidotriphenylphosphanecopperiamp95612bis1pyridin4ylethylidenehydrazine
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