Crystal structure of bis(thiourea-κS)bis(triphenylphosphane-κP)silver(I) nitrate
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the c...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2015-02-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015001395 |
Summary: | In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thiourea S atoms and two triphenylphosphane P atoms in a distorted tetrahedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H...O, C—H...S, N—H...O and N—H...S hydrogen bonds, generating (10-1) sheets. |
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ISSN: | 2056-9890 |