Aqua{2-(morpholin-4-yl)-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)manganese(II)
In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octahedral geometry around the metal atom is completed by two cis-positioned N-bound thiocyanate lig...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811022124 |
| Summary: | In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octahedral geometry around the metal atom is completed by two cis-positioned N-bound thiocyanate ligands and one water molecule. In the crystal, adjacent molecules are linked through O—H...O, O—H...S and C—H...S hydrogen bonds into a three-dimensional supra-molecular structure. An intramolecular C—H...O hydrogen bond also occurs. |
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| ISSN: | 1600-5368 |