catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]

catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]

In the title complex, {[Zn(C7H3NO4)(C12H8N2)]·H2O}n, the ZnII ion is in a distorted octahedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxylate (2,3-pydc) ligands. The bridging 2,3...

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Main Authors: Zhen-Hua Qin, Shu-Fang Lou, Na Wang, Fu-Yu Wang
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811020344
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spelling doaj-b6cc457781a14139ae8dd7f02880426b2020-11-25T01:56:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m864m86410.1107/S1600536811020344catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]Zhen-Hua QinShu-Fang LouNa WangFu-Yu WangIn the title complex, {[Zn(C7H3NO4)(C12H8N2)]·H2O}n, the ZnII ion is in a distorted octahedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxylate (2,3-pydc) ligands. The bridging 2,3-pydc ligands connect the ZnII ions into a chain extending along [010]. O—H...O hydrogen bonds between the uncoordinated water molecules and the uncoordinated carboxylate O atoms, as well as π–π interactions between the pyridine rings of the phen ligands [centroid–centroid distance = 3.557 (2) Å], are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811020344
collection DOAJ
language English
format Article
sources DOAJ
author Zhen-Hua Qin
Shu-Fang Lou
Na Wang
Fu-Yu Wang
spellingShingle Zhen-Hua Qin
Shu-Fang Lou
Na Wang
Fu-Yu Wang
catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
Acta Crystallographica Section E
author_facet Zhen-Hua Qin
Shu-Fang Lou
Na Wang
Fu-Yu Wang
author_sort Zhen-Hua Qin
title catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
title_short catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
title_full catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
title_fullStr catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
title_full_unstemmed catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate]
title_sort catena-poly[[[(1,10-phenanthroline-κ2n,n′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4n,o2:o2′,o3] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the title complex, {[Zn(C7H3NO4)(C12H8N2)]·H2O}n, the ZnII ion is in a distorted octahedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxylate (2,3-pydc) ligands. The bridging 2,3-pydc ligands connect the ZnII ions into a chain extending along [010]. O—H...O hydrogen bonds between the uncoordinated water molecules and the uncoordinated carboxylate O atoms, as well as π–π interactions between the pyridine rings of the phen ligands [centroid–centroid distance = 3.557 (2) Å], are observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811020344
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AT shufanglou catenapoly110phenanthrolineamp9542nnamp8242zincamp956pyridine23dicarboxylatoamp9544no2o2amp8242o3monohydrate
AT nawang catenapoly110phenanthrolineamp9542nnamp8242zincamp956pyridine23dicarboxylatoamp9544no2o2amp8242o3monohydrate
AT fuyuwang catenapoly110phenanthrolineamp9542nnamp8242zincamp956pyridine23dicarboxylatoamp9544no2o2amp8242o3monohydrate
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