Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids
Polysaccharides derived from natural sources exhibit unique structures and functional groups, which have recently garnered them increased attention for their potential applicability as supports for metal catalysts. Renewable polysaccharide matrices were employed as supports for palladium complexes,...
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doaj-b6ed36d5a4134b918d88b4e99fc5b4332020-11-25T00:36:20ZengMDPI AGCatalysts2073-43442020-01-0110113610.3390/catal10010136catal10010136Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic AcidsAdi Wolfson0Oshrat Levy-Ontman1Department of Chemical Engineering, Sami Shamoon College of Engineering, Basel/Bialik Sts., Beer-Sheva 8410001, IsraelDepartment of Chemical Engineering, Sami Shamoon College of Engineering, Basel/Bialik Sts., Beer-Sheva 8410001, IsraelPolysaccharides derived from natural sources exhibit unique structures and functional groups, which have recently garnered them increased attention for their potential applicability as supports for metal catalysts. Renewable polysaccharide matrices were employed as supports for palladium complexes, with or without previous modification of the support, and were used in Suzuki cross-coupling of halobenzenes and phenylboronic acid derivatives. In this review, recent developments in the immobilization of palladium-based complexes are reported, including descriptions of the preparation procedures and catalytic activity of each system. In addition, the effects of the nature of the polymeric support and of the reaction conditions on catalytic performance are discussed.https://www.mdpi.com/2073-4344/10/1/136cross-couplingheterogeneous catalystsimmobilizationpalladiumpolysaccharides suzuki–miyaura |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Adi Wolfson Oshrat Levy-Ontman |
spellingShingle |
Adi Wolfson Oshrat Levy-Ontman Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids Catalysts cross-coupling heterogeneous catalysts immobilization palladium polysaccharides suzuki–miyaura |
author_facet |
Adi Wolfson Oshrat Levy-Ontman |
author_sort |
Adi Wolfson |
title |
Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids |
title_short |
Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids |
title_full |
Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids |
title_fullStr |
Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids |
title_full_unstemmed |
Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids |
title_sort |
recent developments in the immobilization of palladium complexes on renewable polysaccharides for suzuki–miyaura cross-coupling of halobenzenes and phenylboronic acids |
publisher |
MDPI AG |
series |
Catalysts |
issn |
2073-4344 |
publishDate |
2020-01-01 |
description |
Polysaccharides derived from natural sources exhibit unique structures and functional groups, which have recently garnered them increased attention for their potential applicability as supports for metal catalysts. Renewable polysaccharide matrices were employed as supports for palladium complexes, with or without previous modification of the support, and were used in Suzuki cross-coupling of halobenzenes and phenylboronic acid derivatives. In this review, recent developments in the immobilization of palladium-based complexes are reported, including descriptions of the preparation procedures and catalytic activity of each system. In addition, the effects of the nature of the polymeric support and of the reaction conditions on catalytic performance are discussed. |
topic |
cross-coupling heterogeneous catalysts immobilization palladium polysaccharides suzuki–miyaura |
url |
https://www.mdpi.com/2073-4344/10/1/136 |
work_keys_str_mv |
AT adiwolfson recentdevelopmentsintheimmobilizationofpalladiumcomplexesonrenewablepolysaccharidesforsuzukimiyauracrosscouplingofhalobenzenesandphenylboronicacids AT oshratlevyontman recentdevelopmentsintheimmobilizationofpalladiumcomplexesonrenewablepolysaccharidesforsuzukimiyauracrosscouplingofhalobenzenesandphenylboronicacids |
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