A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc
Asimple explanation is offered for the recently discovered chiral amplification in the alkylation reaction of benzaldehyde by means of dialkylzinc, catalyzed by (dimethylamino)isoborneol. The model presentd is similar to, yet somewhat simpler than, the model put forward by Noyori et al.
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Serbian Chemical Society
1999-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/1999/0352-51399908447G.pdf |
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doaj-b70524ae4b6341e2b063137db2751dfc2020-12-18T07:40:09ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74211999-01-01647-844745210.2298/JSC9908447G0352-51399908447GA simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzincGutman Ivan0Faculty of Science, KragujevacAsimple explanation is offered for the recently discovered chiral amplification in the alkylation reaction of benzaldehyde by means of dialkylzinc, catalyzed by (dimethylamino)isoborneol. The model presentd is similar to, yet somewhat simpler than, the model put forward by Noyori et al.http://www.doiserbia.nb.rs/img/doi/0352-5139/1999/0352-51399908447G.pdfchiral stereoselectionchiral amplificationchiral catalysisasymmetric synthesis |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Gutman Ivan |
| spellingShingle |
Gutman Ivan A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc Journal of the Serbian Chemical Society chiral stereoselection chiral amplification chiral catalysis asymmetric synthesis |
| author_facet |
Gutman Ivan |
| author_sort |
Gutman Ivan |
| title |
A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| title_short |
A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| title_full |
A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| title_fullStr |
A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| title_full_unstemmed |
A simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| title_sort |
simple model for chiral amplification in the aminoalcohol-catalyzed reaction of aldehydes with dialkylzinc |
| publisher |
Serbian Chemical Society |
| series |
Journal of the Serbian Chemical Society |
| issn |
0352-5139 1820-7421 |
| publishDate |
1999-01-01 |
| description |
Asimple explanation is offered for the recently discovered chiral
amplification in the alkylation reaction of benzaldehyde by means of
dialkylzinc, catalyzed by (dimethylamino)isoborneol. The model presentd is
similar to, yet somewhat simpler than, the model put forward by Noyori et
al. |
| topic |
chiral stereoselection chiral amplification chiral catalysis asymmetric synthesis |
| url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/1999/0352-51399908447G.pdf |
| work_keys_str_mv |
AT gutmanivan asimplemodelforchiralamplificationintheaminoalcoholcatalyzedreactionofaldehydeswithdialkylzinc AT gutmanivan simplemodelforchiralamplificationintheaminoalcoholcatalyzedreactionofaldehydeswithdialkylzinc |
| _version_ |
1724378693270241280 |