Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions

Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions

A mild and green protocol has been developed for a copper catalyzed N-arylation of anilines and imidazoles under external base/additive, promoter and ligand free conditions. The main advantage of this work is that agro waste WEB (Water Extract of Banana Peel Ash) has emerged as solvent as well as ba...

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Main Authors: Abhijit Mahanta, Ashim J. Thakur, Utpal Bora
Format: Article
Language:English
Published: Elsevier 2021-01-01
Series:Current Research in Green and Sustainable Chemistry
Subjects:
Cross-coupling
N-arylation
WEB
Sustainable
Online Access:http://www.sciencedirect.com/science/article/pii/S2666086521000400
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spelling doaj-b7f522893c63427aa92bd27ff743c1762021-05-02T05:57:25ZengElsevierCurrent Research in Green and Sustainable Chemistry2666-08652021-01-014100093Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditionsAbhijit Mahanta0Ashim J. Thakur1Utpal Bora2Tezpur University (A Central University), Chemical Sciences Department, India; Department of Chemistry, Digboi College, Assam, IndiaTezpur University (A Central University), Chemical Sciences Department, India; Corresponding author.Tezpur University (A Central University), Chemical Sciences Department, India; Corresponding author.A mild and green protocol has been developed for a copper catalyzed N-arylation of anilines and imidazoles under external base/additive, promoter and ligand free conditions. The main advantage of this work is that agro waste WEB (Water Extract of Banana Peel Ash) has emerged as solvent as well as base. The reaction protocol avoids hazardous solvents, toxic chemicals, ligands etc. Interestingly addition of alcoholic co-solvent enhanced the yield of the product.http://www.sciencedirect.com/science/article/pii/S2666086521000400Cross-couplingN-arylationWEBSustainable
collection DOAJ
language English
format Article
sources DOAJ
author Abhijit Mahanta
Ashim J. Thakur
Utpal Bora
spellingShingle Abhijit Mahanta
Ashim J. Thakur
Utpal Bora
Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
Current Research in Green and Sustainable Chemistry
Cross-coupling
N-arylation
WEB
Sustainable
author_facet Abhijit Mahanta
Ashim J. Thakur
Utpal Bora
author_sort Abhijit Mahanta
title Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
title_short Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
title_full Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
title_fullStr Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
title_full_unstemmed Effective utilization of basic nature of WEB in copper catalyzed Chan-Lam N-arylation reaction under ligand free conditions
title_sort effective utilization of basic nature of web in copper catalyzed chan-lam n-arylation reaction under ligand free conditions
publisher Elsevier
series Current Research in Green and Sustainable Chemistry
issn 2666-0865
publishDate 2021-01-01
description A mild and green protocol has been developed for a copper catalyzed N-arylation of anilines and imidazoles under external base/additive, promoter and ligand free conditions. The main advantage of this work is that agro waste WEB (Water Extract of Banana Peel Ash) has emerged as solvent as well as base. The reaction protocol avoids hazardous solvents, toxic chemicals, ligands etc. Interestingly addition of alcoholic co-solvent enhanced the yield of the product.
topic Cross-coupling
N-arylation
WEB
Sustainable
url http://www.sciencedirect.com/science/article/pii/S2666086521000400
work_keys_str_mv AT abhijitmahanta effectiveutilizationofbasicnatureofwebincoppercatalyzedchanlamnarylationreactionunderligandfreeconditions
AT ashimjthakur effectiveutilizationofbasicnatureofwebincoppercatalyzedchanlamnarylationreactionunderligandfreeconditions
AT utpalbora effectiveutilizationofbasicnatureofwebincoppercatalyzedchanlamnarylationreactionunderligandfreeconditions
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