The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns
The uptake capacity of Fe(III) ions by NaY zeolite was investigated in this work. Column experiments were undertaken on continuous systems at 30°C, pH = 3.5, employing a flow rate of 2 m l /min and an average particle size of 0.180 mm. The dynamic system exhibited a distinct ion-exchange mechanism w...
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2007-12-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/026361707785284239 |
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doaj-b8db922ca2384755a5d0f7ea5f2b71102021-04-02T13:04:38ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40382007-12-012510.1260/026361707785284239The Removal of Fe(III) Ions by Adsorption onto Zeolite ColumnsIndianara C. Ostroski0Maria A.S.D. Barros1Edson A. Silva2João H. Dantas3Pedro A. Arroyo4Oswaldo C. Motta Lima5 Chemical Engineering Department, State University of Maringá, Av. Colombo 5790, Bloco D-90, Maringá-PR, Brazil Chemical Engineering Department, State University of Maringá, Av. Colombo 5790, Bloco D-90, Maringá-PR, Brazil Chemical Engineering Department, West State University of Paraná, Toledo-PR, Brazil Chemical Engineering Department, State University of Maringá, Av. Colombo 5790, Bloco D-90, Maringá-PR, Brazil Chemical Engineering Department, State University of Maringá, Av. Colombo 5790, Bloco D-90, Maringá-PR, Brazil Chemical Engineering Department, State University of Maringá, Av. Colombo 5790, Bloco D-90, Maringá-PR, BrazilThe uptake capacity of Fe(III) ions by NaY zeolite was investigated in this work. Column experiments were undertaken on continuous systems at 30°C, pH = 3.5, employing a flow rate of 2 m l /min and an average particle size of 0.180 mm. The dynamic system exhibited a distinct ion-exchange mechanism which generated a favourable isotherm with an Fe(III) ion uptake of 2.16 mequiv/g. A mathematical model was also applied to represent the dynamics of the sorption process. The dynamic isotherm was successfully modelled by the Langmuir equation while the mathematical model gave a good description of the experimental dynamic data for feed concentrations ranging from 0.2 mequiv/ l to 3.5 mequiv/ l . The ion-exchange kinetics for Fe(III) ions were studied using the first-, second-order and Langmuir kinetic models.https://doi.org/10.1260/026361707785284239 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Indianara C. Ostroski Maria A.S.D. Barros Edson A. Silva João H. Dantas Pedro A. Arroyo Oswaldo C. Motta Lima |
spellingShingle |
Indianara C. Ostroski Maria A.S.D. Barros Edson A. Silva João H. Dantas Pedro A. Arroyo Oswaldo C. Motta Lima The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns Adsorption Science & Technology |
author_facet |
Indianara C. Ostroski Maria A.S.D. Barros Edson A. Silva João H. Dantas Pedro A. Arroyo Oswaldo C. Motta Lima |
author_sort |
Indianara C. Ostroski |
title |
The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns |
title_short |
The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns |
title_full |
The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns |
title_fullStr |
The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns |
title_full_unstemmed |
The Removal of Fe(III) Ions by Adsorption onto Zeolite Columns |
title_sort |
removal of fe(iii) ions by adsorption onto zeolite columns |
publisher |
Hindawi - SAGE Publishing |
series |
Adsorption Science & Technology |
issn |
0263-6174 2048-4038 |
publishDate |
2007-12-01 |
description |
The uptake capacity of Fe(III) ions by NaY zeolite was investigated in this work. Column experiments were undertaken on continuous systems at 30°C, pH = 3.5, employing a flow rate of 2 m l /min and an average particle size of 0.180 mm. The dynamic system exhibited a distinct ion-exchange mechanism which generated a favourable isotherm with an Fe(III) ion uptake of 2.16 mequiv/g. A mathematical model was also applied to represent the dynamics of the sorption process. The dynamic isotherm was successfully modelled by the Langmuir equation while the mathematical model gave a good description of the experimental dynamic data for feed concentrations ranging from 0.2 mequiv/ l to 3.5 mequiv/ l . The ion-exchange kinetics for Fe(III) ions were studied using the first-, second-order and Langmuir kinetic models. |
url |
https://doi.org/10.1260/026361707785284239 |
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