The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted phenyl)acetic acids

The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted phenyl)acetic acids

The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic equation, of the form: log k = log k0 + sp* + aa...

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Bibliographic Details
Main Authors: VERA V. KRSTIC, GORDANA S. USCUMLIC, JASMINA B. NIKOLIC
Format: Article
Language:English
Published: Serbian Chemical Society 2004-09-01
Series:Journal of the Serbian Chemical Society
Subjects:
2-(2-substitued cyclohex-1-enyl)acetic acids
2-(2-substituted phenyl)acetic acids
diazodiphenylmethane
kinetic measurements
protic solvents
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol69/No8-9/V69-No8_9-01.pdf

Internet

http://www.shd.org.yu/HtDocs/SHD/Vol69/No8-9/V69-No8_9-01.pdf

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