Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)

Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)

In the title compound, [NdCl3(C12H10N2O)3], the central NdIII ion is nine-coordinated by six N atoms from three bidentate chelate N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine ligands and three Cl− ions, and displays a distorted tricapped trigonal prismatic geometry. The complex mol...

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Main Author: Hua Yang
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812014055
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spelling doaj-b92676fa84ae47488932f744fc2ba7332020-11-25T01:17:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m578m57910.1107/S1600536812014055Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)Hua YangIn the title compound, [NdCl3(C12H10N2O)3], the central NdIII ion is nine-coordinated by six N atoms from three bidentate chelate N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine ligands and three Cl− ions, and displays a distorted tricapped trigonal prismatic geometry. The complex molecules are stabilized by intramolecular O—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812014055
collection DOAJ
language English
format Article
sources DOAJ
author Hua Yang
spellingShingle Hua Yang
Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
Acta Crystallographica Section E
author_facet Hua Yang
author_sort Hua Yang
title Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
title_short Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
title_full Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
title_fullStr Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
title_full_unstemmed Trichloridotris{N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2N,N′}neodymium(III)
title_sort trichloridotris{n-[phenyl(pyridin-2-yl)methylidene]hydroxylamine-κ2n,n′}neodymium(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description In the title compound, [NdCl3(C12H10N2O)3], the central NdIII ion is nine-coordinated by six N atoms from three bidentate chelate N-[phenyl(pyridin-2-yl)methylidene]hydroxylamine ligands and three Cl− ions, and displays a distorted tricapped trigonal prismatic geometry. The complex molecules are stabilized by intramolecular O—H...Cl hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812014055
work_keys_str_mv AT huayang trichloridotrisnphenylpyridin2ylmethylidenehydroxylamineamp9542nnamp8242neodymiumiii
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