μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate
The asymmetric unit of the title compound, [Rb2(P2S6)(C12H24O6)2]·2CH3CN, contains one half of an [Rb(18-crown-6)2]2[P2S6] unit and one acetonitrile solvent molecule. The [Rb(18-crown-6)]2[P2S6] unit is completed by inversion symmetry. Its Rb+ ion is situated near the centre of the macrocyc...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2013-12-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813032121 |
id |
doaj-b9b4f89595984b3bbca17b5f1a10d032 |
---|---|
record_format |
Article |
spelling |
doaj-b9b4f89595984b3bbca17b5f1a10d0322020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912m689m68910.1107/S1600536813032121μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvateFlora QarriNiels-Patrick PookMimoza GjikajThe asymmetric unit of the title compound, [Rb2(P2S6)(C12H24O6)2]·2CH3CN, contains one half of an [Rb(18-crown-6)2]2[P2S6] unit and one acetonitrile solvent molecule. The [Rb(18-crown-6)]2[P2S6] unit is completed by inversion symmetry. Its Rb+ ion is situated near the centre of the macrocyclic cavity, but is displaced by 0.8972 (1) Å from the O atoms of the crown in the direction of the [P2S6]2− moiety. The overall coordination number of the cation is eight, defined by the six crown ether O atoms and by two terminal S atoms of the [P2S6]2− anion. The hexathiometadiphosphate anion is built up from two tetrahedral PS4 units joined together by a common edge. The crystal structure is characterized by alternating layers of [Rb(18-crown-6)]2[P2S6] and acetonitrile solvent molecules stacked along [010].http://scripts.iucr.org/cgi-bin/paper?S1600536813032121 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Flora Qarri Niels-Patrick Pook Mimoza Gjikaj |
spellingShingle |
Flora Qarri Niels-Patrick Pook Mimoza Gjikaj μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate Acta Crystallographica Section E |
author_facet |
Flora Qarri Niels-Patrick Pook Mimoza Gjikaj |
author_sort |
Flora Qarri |
title |
μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate |
title_short |
μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate |
title_full |
μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate |
title_fullStr |
μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate |
title_full_unstemmed |
μ-Hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6O)rubidium] acetonitrile disolvate |
title_sort |
μ-hexathiometadiphosphato-bis[(1,4,7,10,13,16-hexaoxacyclooctadecane-κ6o)rubidium] acetonitrile disolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2013-12-01 |
description |
The asymmetric unit of the title compound, [Rb2(P2S6)(C12H24O6)2]·2CH3CN, contains one half of an [Rb(18-crown-6)2]2[P2S6] unit and one acetonitrile solvent molecule. The [Rb(18-crown-6)]2[P2S6] unit is completed by inversion symmetry. Its Rb+ ion is situated near the centre of the macrocyclic cavity, but is displaced by 0.8972 (1) Å from the O atoms of the crown in the direction of the [P2S6]2− moiety. The overall coordination number of the cation is eight, defined by the six crown ether O atoms and by two terminal S atoms of the [P2S6]2− anion. The hexathiometadiphosphate anion is built up from two tetrahedral PS4 units joined together by a common edge. The crystal structure is characterized by alternating layers of [Rb(18-crown-6)]2[P2S6] and acetonitrile solvent molecules stacked along [010]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813032121 |
work_keys_str_mv |
AT floraqarri 956hexathiometadiphosphatobis147101316hexaoxacyclooctadecane9546orubidiumacetonitriledisolvate AT nielspatrickpook 956hexathiometadiphosphatobis147101316hexaoxacyclooctadecane9546orubidiumacetonitriledisolvate AT mimozagjikaj 956hexathiometadiphosphatobis147101316hexaoxacyclooctadecane9546orubidiumacetonitriledisolvate |
_version_ |
1725979879060537344 |