Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate

Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate

In the mononuclear title salt, [Ag(C3H8N2S)(C18H15P)3](CH3COO), the AgI ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the comp...

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Main Authors: Yupa Wattanakanjana, Arunpatcha Nimthong, Chanokphat Darasuriyong
Format: Article
Language:English
Published: International Union of Crystallography 2014-09-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
1,3-dimethylthiourea
silver complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814019047
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spelling doaj-ba49b1a7e6bd4dbf89461c73252b49f22020-11-25T00:48:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709m337m33810.1107/S1600536814019047wm5052Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetateYupa Wattanakanjana0Arunpatcha Nimthong1Chanokphat Darasuriyong2Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandDepartment of Chemistry, Youngstown State University, 1 University Plaza, 44555 Youngstown, OH, USADepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, ThailandIn the mononuclear title salt, [Ag(C3H8N2S)(C18H15P)3](CH3COO), the AgI ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—H...O hydrogen bonds [graph-set motif R22(8)].http://scripts.iucr.org/cgi-bin/paper?S1600536814019047crystal structure1,3-dimethylthioureasilver complex
collection DOAJ
language English
format Article
sources DOAJ
author Yupa Wattanakanjana
Arunpatcha Nimthong
Chanokphat Darasuriyong
spellingShingle Yupa Wattanakanjana
Arunpatcha Nimthong
Chanokphat Darasuriyong
Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
Acta Crystallographica Section E
crystal structure
1,3-dimethylthiourea
silver complex
author_facet Yupa Wattanakanjana
Arunpatcha Nimthong
Chanokphat Darasuriyong
author_sort Yupa Wattanakanjana
title Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
title_short Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
title_full Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
title_fullStr Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
title_full_unstemmed Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
title_sort crystal structure of (1,3-dimethylthiourea-κs)tris(triphenylphosphane-κp)silver(i) acetate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-09-01
description In the mononuclear title salt, [Ag(C3H8N2S)(C18H15P)3](CH3COO), the AgI ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—H...O hydrogen bonds [graph-set motif R22(8)].
topic crystal structure
1,3-dimethylthiourea
silver complex
url http://scripts.iucr.org/cgi-bin/paper?S1600536814019047
work_keys_str_mv AT yupawattanakanjana crystalstructureof13dimethylthioureakstristriphenylphosphanekpsilveriacetate
AT arunpatchanimthong crystalstructureof13dimethylthioureakstristriphenylphosphanekpsilveriacetate
AT chanokphatdarasuriyong crystalstructureof13dimethylthioureakstristriphenylphosphanekpsilveriacetate
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