{4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)

{4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)

The title compound, [Zn(C13H16BrN2O2)I(CH3OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quantities of 5-bromosalicylaldehyde, 2-morpholinoethylamine and ZnI2 in methanol. The Zn atom is four-coordinate in a distorted tetrahedral geometry, binding to a phenolate...

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Main Author: Cheng-Li Han
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809009234
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spelling doaj-ba9c0a1015f94bb7a88e73e85f7c10fc2020-11-25T01:15:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m418m41810.1107/S1600536809009234{4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)Cheng-Li HanThe title compound, [Zn(C13H16BrN2O2)I(CH3OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quantities of 5-bromosalicylaldehyde, 2-morpholinoethylamine and ZnI2 in methanol. The Zn atom is four-coordinate in a distorted tetrahedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol molecule and one I− anion. In the crystal structure, adjacent molecules are linked through intermolecular O—H...O hydrogen bonds, forming centrosymmetric dimers. http://scripts.iucr.org/cgi-bin/paper?S1600536809009234
collection DOAJ
language English
format Article
sources DOAJ
author Cheng-Li Han
spellingShingle Cheng-Li Han
{4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
Acta Crystallographica Section E
author_facet Cheng-Li Han
author_sort Cheng-Li Han
title {4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
title_short {4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
title_full {4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
title_fullStr {4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
title_full_unstemmed {4-Bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(II)
title_sort {4-bromo-2-[(2-morpholinoethyl)iminomethyl]phenolato}iodido(methanol)zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description The title compound, [Zn(C13H16BrN2O2)I(CH3OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quantities of 5-bromosalicylaldehyde, 2-morpholinoethylamine and ZnI2 in methanol. The Zn atom is four-coordinate in a distorted tetrahedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol molecule and one I− anion. In the crystal structure, adjacent molecules are linked through intermolecular O—H...O hydrogen bonds, forming centrosymmetric dimers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809009234
work_keys_str_mv AT chenglihan 4bromo22morpholinoethyliminomethylphenolatoiodidomethanolzincii
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