Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill

Tension (TW) and opposite wood (OW) of Eucalyptus globulus trees were analyzed for its chemical characteristics and Kraft pulp production. Lignin content was 16% lower and contained 32% more syringyl units in TW than in OW. The increase in syringyl units favoured the formation of β-O-4 bonds that wa...

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Main Authors: María Graciela Aguayo, Regis Teixeira Mendonça, Paulina Martínez, Jaime Rodríguez, Miguel Pereira
Format: Article
Language:English
Published: Sociedade de Investigações Florestais 2012-12-01
Series:Revista Árvore
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-67622012000600017&lng=en&tlng=en
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spelling doaj-bb0ef5f195ed45cbbf865745aa2eb4ca2020-11-24T23:14:23ZengSociedade de Investigações FlorestaisRevista Árvore1806-90882012-12-013661163117210.1590/S0100-67622012000600017S0100-67622012000600017Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labillMaría Graciela Aguayo0Regis Teixeira Mendonça1Paulina Martínez2Jaime Rodríguez3Miguel Pereira4Universidad de ConcepciónUniversidad de ConcepciónUniversidad de ConcepciónUniversidad de ConcepciónUniversidad de ConcepciónTension (TW) and opposite wood (OW) of Eucalyptus globulus trees were analyzed for its chemical characteristics and Kraft pulp production. Lignin content was 16% lower and contained 32% more syringyl units in TW than in OW. The increase in syringyl units favoured the formation of β-O-4 bonds that was also higher in TW than in OW (84% vs. 64%, respectively). The effect of these wood features was evaluated in the production of Kraft pulps from both types of wood. At kappa number 16, Kraft pulps obtained from TW demanded less active alkali in delignification and presented slightly higher or similar pulp yield than pulps made with OW. Fiber length, coarseness and intrinsic viscosity were also higher in tension than in opposite pulps. When pulps where refined to 30°SR, TW pulps needed 18% more revolutions in the PFI mill to achieve the same beating degree than OW pulps. Strength properties (tensile, tear and burst indexes) were slightly higher or similar in tension as compared with opposite wood pulps. After an OD0(EO)D1 bleaching sequence, both pulps achieved up to 89% ISO brightness. Bleached pulps from TW presented higher viscosity and low amount of hexenuronic acids than pulps from OW. Results showed that TW presented high xylans and low lignin content that caused a decrease in alkali consumption, increase pulp strength properties and similar bleaching performance as compared with pulps from OW.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-67622012000600017&lng=en&tlng=enEucalyptus globulusMadeira de reaçãoPolpação KraftXilanasEstrutura da lignina
collection DOAJ
language English
format Article
sources DOAJ
author María Graciela Aguayo
Regis Teixeira Mendonça
Paulina Martínez
Jaime Rodríguez
Miguel Pereira
spellingShingle María Graciela Aguayo
Regis Teixeira Mendonça
Paulina Martínez
Jaime Rodríguez
Miguel Pereira
Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
Revista Árvore
Eucalyptus globulus
Madeira de reação
Polpação Kraft
Xilanas
Estrutura da lignina
author_facet María Graciela Aguayo
Regis Teixeira Mendonça
Paulina Martínez
Jaime Rodríguez
Miguel Pereira
author_sort María Graciela Aguayo
title Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
title_short Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
title_full Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
title_fullStr Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
title_full_unstemmed Chemical characteristics and Kraft pulping of tension wood from Eucalyptus globulus labill
title_sort chemical characteristics and kraft pulping of tension wood from eucalyptus globulus labill
publisher Sociedade de Investigações Florestais
series Revista Árvore
issn 1806-9088
publishDate 2012-12-01
description Tension (TW) and opposite wood (OW) of Eucalyptus globulus trees were analyzed for its chemical characteristics and Kraft pulp production. Lignin content was 16% lower and contained 32% more syringyl units in TW than in OW. The increase in syringyl units favoured the formation of β-O-4 bonds that was also higher in TW than in OW (84% vs. 64%, respectively). The effect of these wood features was evaluated in the production of Kraft pulps from both types of wood. At kappa number 16, Kraft pulps obtained from TW demanded less active alkali in delignification and presented slightly higher or similar pulp yield than pulps made with OW. Fiber length, coarseness and intrinsic viscosity were also higher in tension than in opposite pulps. When pulps where refined to 30°SR, TW pulps needed 18% more revolutions in the PFI mill to achieve the same beating degree than OW pulps. Strength properties (tensile, tear and burst indexes) were slightly higher or similar in tension as compared with opposite wood pulps. After an OD0(EO)D1 bleaching sequence, both pulps achieved up to 89% ISO brightness. Bleached pulps from TW presented higher viscosity and low amount of hexenuronic acids than pulps from OW. Results showed that TW presented high xylans and low lignin content that caused a decrease in alkali consumption, increase pulp strength properties and similar bleaching performance as compared with pulps from OW.
topic Eucalyptus globulus
Madeira de reação
Polpação Kraft
Xilanas
Estrutura da lignina
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-67622012000600017&lng=en&tlng=en
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