trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
The complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbo...
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International Union of Crystallography
2009-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809032152 |
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doaj-bbe11c95cec54c418b7e9346ff2f97e12020-11-25T02:15:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1080m108110.1107/S1600536809032152trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]El Adoui LaifaLamia BendjeddouNaouel BoudraaSlimane DahaouiClaude LecomteThe complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S...S interactions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809032152 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
El Adoui Laifa Lamia Bendjeddou Naouel Boudraa Slimane Dahaoui Claude Lecomte |
spellingShingle |
El Adoui Laifa Lamia Bendjeddou Naouel Boudraa Slimane Dahaoui Claude Lecomte trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] Acta Crystallographica Section E |
author_facet |
El Adoui Laifa Lamia Bendjeddou Naouel Boudraa Slimane Dahaoui Claude Lecomte |
author_sort |
El Adoui Laifa |
title |
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] |
title_short |
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] |
title_full |
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] |
title_fullStr |
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] |
title_full_unstemmed |
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)] |
title_sort |
trans-di-μ-iodido-bis[(3h-1,2-benzodithiole-3-thione)iodidomercury(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-09-01 |
description |
The complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S...S interactions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809032152 |
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