trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]

trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]

The complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbo...

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Main Authors: El Adoui Laifa, Lamia Bendjeddou, Naouel Boudraa, Slimane Dahaoui, Claude Lecomte
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809032152
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spelling doaj-bbe11c95cec54c418b7e9346ff2f97e12020-11-25T02:15:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1080m108110.1107/S1600536809032152trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]El Adoui LaifaLamia BendjeddouNaouel BoudraaSlimane DahaouiClaude LecomteThe complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S...S interactions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809032152
collection DOAJ
language English
format Article
sources DOAJ
author El Adoui Laifa
Lamia Bendjeddou
Naouel Boudraa
Slimane Dahaoui
Claude Lecomte
spellingShingle El Adoui Laifa
Lamia Bendjeddou
Naouel Boudraa
Slimane Dahaoui
Claude Lecomte
trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
Acta Crystallographica Section E
author_facet El Adoui Laifa
Lamia Bendjeddou
Naouel Boudraa
Slimane Dahaoui
Claude Lecomte
author_sort El Adoui Laifa
title trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_short trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_full trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_fullStr trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_full_unstemmed trans-Di-μ-iodido-bis[(3H-1,2-benzodithiole-3-thione)iodidomercury(II)]
title_sort trans-di-μ-iodido-bis[(3h-1,2-benzodithiole-3-thione)iodidomercury(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description The complete molecule of the dinuclear title compound, [Hg2I4(C7H4S3)2], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each HgII ion adopts a tetrahedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thiocarbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S...S interactions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809032152
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AT naouelboudraa transdiamp956iodidobis3h12benzodithiole3thioneiodidomercuryii
AT slimanedahaoui transdiamp956iodidobis3h12benzodithiole3thioneiodidomercuryii
AT claudelecomte transdiamp956iodidobis3h12benzodithiole3thioneiodidomercuryii
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