(Acetylacetonato-κ2O,O′)carbonyl{dicyclohexyl[4-(dimethylamino)phenyl]phosphane-κP}rhodium(I)
The title compound, [Rh(C5H7O2)(C20H32NP)(CO)], features an acetylacetonate-chelated RhI cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh&...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811050483 |
| Summary: | The title compound, [Rh(C5H7O2)(C20H32NP)(CO)], features an acetylacetonate-chelated RhI cation coordinated by one P [Rh—P = 2.2525 (7) Å], one carbonyl C [Rh—C = 1.792 (3) Å] and two O [Rh—O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Molecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh–acetylacetonate backbone. |
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| ISSN: | 1600-5368 |