catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate]
The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water mol...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812018752 |
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Article |
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doaj-bd414a5cb8694a52b215406b043713c02020-11-25T02:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m721m72110.1107/S1600536812018752catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate]Xiang-Qian FangShan GaoSeik Weng NgThe 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H...O hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812018752 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Xiang-Qian Fang Shan Gao Seik Weng Ng |
| spellingShingle |
Xiang-Qian Fang Shan Gao Seik Weng Ng catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] Acta Crystallographica Section E |
| author_facet |
Xiang-Qian Fang Shan Gao Seik Weng Ng |
| author_sort |
Xiang-Qian Fang |
| title |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] |
| title_short |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] |
| title_full |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] |
| title_fullStr |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] |
| title_full_unstemmed |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2O3:O1] sesquihydrate] |
| title_sort |
catena-poly[[[diaqua(1,10-phenanthroline-κ2n,n′)cobalt(ii)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2o3:o1] sesquihydrate] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-06-01 |
| description |
The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H...O hydrogen bonds into a three-dimensional network. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812018752 |
| work_keys_str_mv |
AT xiangqianfang catenapolydiaqua110phenanthrolineamp9542nnamp8242cobaltiiamp9564hydroxy3sulfonatobenzoatoamp9542o3o1sesquihydrate AT shangao catenapolydiaqua110phenanthrolineamp9542nnamp8242cobaltiiamp9564hydroxy3sulfonatobenzoatoamp9542o3o1sesquihydrate AT seikwengng catenapolydiaqua110phenanthrolineamp9542nnamp8242cobaltiiamp9564hydroxy3sulfonatobenzoatoamp9542o3o1sesquihydrate |
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