Stereoselective oxidative glycosylation of anomeric nucleophiles with alcohols and carboxylic acids

Glycosylation of partially protected sugars is usually limited by suboptimal regio- and stereo-selectivities. Here, the authors show a general oxidative glycosylation between anomeric stannanes with a nonprotected hydroxyl group and oxygen nucleophiles, additionally providing mechanistic insights in...

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Bibliographic Details
Main Authors: Tianyi Yang, Feng Zhu, Maciej A. Walczak
Format: Article
Language:English
Published: Nature Publishing Group 2018-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-06016-4