Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes

Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes

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Terminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.

Bibliographic Details
Main Authors: XIAN HUANG, PING ZHONG
Format: Article
Language:English
Published: Serbian Chemical Society 2004-03-01
Series:Journal of the Serbian Chemical Society
Subjects:
alkyne
sulfide
alkylsulfenyl chloride
hydrozirconation
synthesis
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol69/No3/V69-No3-01.pdf
Description
Summary:Terminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.
ISSN:0352-5139

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