Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes

Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes

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Terminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.

Bibliographic Details
Main Authors: XIAN HUANG, PING ZHONG
Format: Article
Language:English
Published: Serbian Chemical Society 2004-03-01
Series:Journal of the Serbian Chemical Society
Subjects:
alkyne
sulfide
alkylsulfenyl chloride
hydrozirconation
synthesis
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol69/No3/V69-No3-01.pdf
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spelling doaj-bd530d5fbb91436d962d1679d557102d2020-11-25T00:18:22ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51392004-03-01693175178Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynesXIAN HUANGPING ZHONGTerminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.http://www.shd.org.yu/HtDocs/SHD/Vol69/No3/V69-No3-01.pdfalkynesulfidealkylsulfenyl chloridehydrozirconationsynthesis
collection DOAJ
language English
format Article
sources DOAJ
author XIAN HUANG
PING ZHONG
spellingShingle XIAN HUANG
PING ZHONG
Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
Journal of the Serbian Chemical Society
alkyne
sulfide
alkylsulfenyl chloride
hydrozirconation
synthesis
author_facet XIAN HUANG
PING ZHONG
author_sort XIAN HUANG
title Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
title_short Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
title_full Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
title_fullStr Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
title_full_unstemmed Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
title_sort stereoselective synthesis of (e)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes
publisher Serbian Chemical Society
series Journal of the Serbian Chemical Society
issn 0352-5139
publishDate 2004-03-01
description Terminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.
topic alkyne
sulfide
alkylsulfenyl chloride
hydrozirconation
synthesis
url http://www.shd.org.yu/HtDocs/SHD/Vol69/No3/V69-No3-01.pdf
work_keys_str_mv AT xianhuang stereoselectivesynthesisofevinylalkylsulfidesviahydrozirconationofterminalalkynes
AT pingzhong stereoselectivesynthesisofevinylalkylsulfidesviahydrozirconationofterminalalkynes
_version_ 1725376952426037248

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