Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]

Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]

The title dinuclear complex, [Re2(C13H8NOS)2(CO)6], crystallizes in two polymorphs where the 2-(1,3-benzothiazol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re2O2(CO)4] core. Polymorphs I and II exhibit a crystallographically imposed centre...

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Main Authors: Maruthupandiyan Priyatharsini, Bhaskaran Shankar, Malaichamy Sathiyendiran, Navaneethakrishnan Srinivasan, Rajaputi Venkatraman Krishnakumar
Format: Article
Language:English
Published: International Union of Crystallography 2017-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
rhenium tricarbonyl complexes
polymorphism
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017001347
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spelling doaj-bde761fa391d4eca87abb670f41803ad2020-11-24T22:37:18ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-02-0173231031310.1107/S2056989017001347rz5204Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]Maruthupandiyan Priyatharsini0Bhaskaran Shankar1Malaichamy Sathiyendiran2Navaneethakrishnan Srinivasan3Rajaputi Venkatraman Krishnakumar4Department of Physics, Thiagarajar College, Madurai 625 009, Tamil Nadu, IndiaDepartment of Chemistry, University of Hyderabad, South Campus, Hyderabad 500 046, Telengana, IndiaDepartment of Chemistry, University of Hyderabad, South Campus, Hyderabad 500 046, Telengana, IndiaDepartment of Physics, Thiagarajar College, Madurai 625 009, Tamil Nadu, IndiaDepartment of Physics, Thiagarajar College, Madurai 625 009, Tamil Nadu, IndiaThe title dinuclear complex, [Re2(C13H8NOS)2(CO)6], crystallizes in two polymorphs where the 2-(1,3-benzothiazol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re2O2(CO)4] core. Polymorphs I and II exhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structures may be described as being formed by two octahedrally distorted metal-coordinating units fused through μ-oxido bridges, leading to edge-sharing dimers. The crystal packing is governed by C—H...O hydrogen-bonding interactions, forming chains parallel to the c axis in I and a three-dimensional network in II.http://scripts.iucr.org/cgi-bin/paper?S2056989017001347crystal structurerhenium tricarbonyl complexespolymorphism
collection DOAJ
language English
format Article
sources DOAJ
author Maruthupandiyan Priyatharsini
Bhaskaran Shankar
Malaichamy Sathiyendiran
Navaneethakrishnan Srinivasan
Rajaputi Venkatraman Krishnakumar
spellingShingle Maruthupandiyan Priyatharsini
Bhaskaran Shankar
Malaichamy Sathiyendiran
Navaneethakrishnan Srinivasan
Rajaputi Venkatraman Krishnakumar
Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
rhenium tricarbonyl complexes
polymorphism
author_facet Maruthupandiyan Priyatharsini
Bhaskaran Shankar
Malaichamy Sathiyendiran
Navaneethakrishnan Srinivasan
Rajaputi Venkatraman Krishnakumar
author_sort Maruthupandiyan Priyatharsini
title Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
title_short Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
title_full Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
title_fullStr Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
title_full_unstemmed Crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3N,O:O;κ3O:N,O-bis[fac-tricarbonylrhenium(I)]
title_sort crystal structure of the cis and trans polymorphs of bis[μ-2-(1,3-benzothiazol-2-yl)phenolato]-κ3n,o:o;κ3o:n,o-bis[fac-tricarbonylrhenium(i)]
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2017-02-01
description The title dinuclear complex, [Re2(C13H8NOS)2(CO)6], crystallizes in two polymorphs where the 2-(1,3-benzothiazol-2-yl)phenolate ligands and two carbonyl groups are trans- (I) or cis-arranged (II) with respect to the [Re2O2(CO)4] core. Polymorphs I and II exhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structures may be described as being formed by two octahedrally distorted metal-coordinating units fused through μ-oxido bridges, leading to edge-sharing dimers. The crystal packing is governed by C—H...O hydrogen-bonding interactions, forming chains parallel to the c axis in I and a three-dimensional network in II.
topic crystal structure
rhenium tricarbonyl complexes
polymorphism
url http://scripts.iucr.org/cgi-bin/paper?S2056989017001347
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AT bhaskaranshankar crystalstructureofthecisandtranspolymorphsofbism213benzothiazol2ylphenolatok3nook3onobisfactricarbonylrheniumi
AT malaichamysathiyendiran crystalstructureofthecisandtranspolymorphsofbism213benzothiazol2ylphenolatok3nook3onobisfactricarbonylrheniumi
AT navaneethakrishnansrinivasan crystalstructureofthecisandtranspolymorphsofbism213benzothiazol2ylphenolatok3nook3onobisfactricarbonylrheniumi
AT rajaputivenkatramankrishnakumar crystalstructureofthecisandtranspolymorphsofbism213benzothiazol2ylphenolatok3nook3onobisfactricarbonylrheniumi
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