Elastic Properties of 4–6 nm-thick Glassy Carbon Thin Films

<p>Abstract</p> <p>Glassy carbon is a disordered, nanoporous form of carbon with superior thermal and chemical stability in extreme environments. Freestanding glassy carbon specimens with 4&#8211;6 nm thickness and 0.5 nm average pore size were synthesized and fabricated from p...

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Bibliographic Details
Main Authors: Lee H, Rajagopalan R, Foley HC, Manoharan MP, Haque MA
Format: Article
Language:English
Published: SpringerOpen 2009-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-009-9435-2
Description
Summary:<p>Abstract</p> <p>Glassy carbon is a disordered, nanoporous form of carbon with superior thermal and chemical stability in extreme environments. Freestanding glassy carbon specimens with 4&#8211;6 nm thickness and 0.5 nm average pore size were synthesized and fabricated from polyfurfuryl alcohol precursors. Elastic properties of the specimens were measured in situ inside a scanning electron microscope using a custom-built micro-electro-mechanical system. The Young&#8217;s modulus, fracture stress and strain values were measured to be about 62 GPa, 870 MPa and 1.3%, respectively; showing strong size effects compared to a modulus value of 30 GPa at the bulk scale. This size effect is explained on the basis of the increased significance of surface elastic properties at the nanometer length-scale.</p>
ISSN:1931-7573
1556-276X