Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery

In this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were inv...

Full description

Bibliographic Details
Main Authors:	Murukanahally Kempaiah Devaraju, Quang Duc Truong, Hiroshi Hyodo, Takaaki Tomai, Itaru Honma
Format:	Article
Language:	English
Published:	MDPI AG 2014-05-01
Series:	Inorganics
Subjects:	supercritical fluid starting materials high voltage nanoparticles LiCoPO4 cathode
Online Access:	http://www.mdpi.com/2304-6740/2/2/233

id	doaj-be024f3b536646a1a45de41bee552724
record_format	Article
spelling	doaj-be024f3b536646a1a45de41bee5527242020-11-25T00:36:25ZengMDPI AGInorganics2304-67402014-05-012223324710.3390/inorganics2020233inorganics2020233Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion BatteryMurukanahally Kempaiah Devaraju0Quang Duc Truong1Hiroshi Hyodo2Takaaki Tomai3Itaru Honma4Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, JapanInstitute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku, Sendai 980-8577, JapanIn this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were investigated. The as-synthesized samples were systematically characterized by XRD, TEM, STEM, EDS, BET, and TG and charge-discharge measurements. In addition, Rietveld refinement analysis was performed. The electrochemical measurements of LiCoPO4 nanoparticles have shown differences in capacities depending on the starting materials used in the synthesis and the results have been discussed in this paper.http://www.mdpi.com/2304-6740/2/2/233supercritical fluidstarting materialshigh voltagenanoparticlesLiCoPO4 cathode
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Murukanahally Kempaiah Devaraju Quang Duc Truong Hiroshi Hyodo Takaaki Tomai Itaru Honma
spellingShingle	Murukanahally Kempaiah Devaraju Quang Duc Truong Hiroshi Hyodo Takaaki Tomai Itaru Honma Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery Inorganics supercritical fluid starting materials high voltage nanoparticles LiCoPO4 cathode
author_facet	Murukanahally Kempaiah Devaraju Quang Duc Truong Hiroshi Hyodo Takaaki Tomai Itaru Honma
author_sort	Murukanahally Kempaiah Devaraju
title	Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
title_short	Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
title_full	Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
title_fullStr	Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
title_full_unstemmed	Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery
title_sort	supercritical fluid synthesis of licopo4 nanoparticles and their application to lithium ion battery
publisher	MDPI AG
series	Inorganics
issn	2304-6740
publishDate	2014-05-01
description	In this work, LiCoPO4 nanoparticles were synthesized by supercritical fluid method using cobalt nitrate hexahydrate (Co(NO3)2 6H2O) and cobalt acetate tetrahydrate (C4H6CoO4 4H2O) as starting materials. The effect of starting materials on particle morphology, size, and the crystalline phase were investigated. The as-synthesized samples were systematically characterized by XRD, TEM, STEM, EDS, BET, and TG and charge-discharge measurements. In addition, Rietveld refinement analysis was performed. The electrochemical measurements of LiCoPO4 nanoparticles have shown differences in capacities depending on the starting materials used in the synthesis and the results have been discussed in this paper.
topic	supercritical fluid starting materials high voltage nanoparticles LiCoPO4 cathode
url	http://www.mdpi.com/2304-6740/2/2/233
work_keys_str_mv	AT murukanahallykempaiahdevaraju supercriticalfluidsynthesisoflicopo4nanoparticlesandtheirapplicationtolithiumionbattery AT quangductruong supercriticalfluidsynthesisoflicopo4nanoparticlesandtheirapplicationtolithiumionbattery AT hiroshihyodo supercriticalfluidsynthesisoflicopo4nanoparticlesandtheirapplicationtolithiumionbattery AT takaakitomai supercriticalfluidsynthesisoflicopo4nanoparticlesandtheirapplicationtolithiumionbattery AT itaruhonma supercriticalfluidsynthesisoflicopo4nanoparticlesandtheirapplicationtolithiumionbattery
_version_	1725305473701249024

Supercritical Fluid Synthesis of LiCoPO4 Nanoparticles and Their Application to Lithium Ion Battery

Similar Items