Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.

Bibliographic Details
Main Authors: Florent Allais, Jean Boivin, Van Tai Nguyen
Format: Article
Language:English
Published: Beilstein-Institut 2007-12-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-3-46
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spelling doaj-be2d0b08603d44edb6334ace364f60682021-02-02T07:54:13ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972007-12-01314610.1186/1860-5397-3-461860-5397-3-46Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and airFlorent Allais0Jean Boivin1Van Tai Nguyen2Institut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceInstitut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceInstitut de Chimie des Substances Naturelles, C.N.R.S., Avenue de la Terrasse, 91198 Gif-sur-Yvette, FranceExperiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.https://doi.org/10.1186/1860-5397-3-46
collection DOAJ
language English
format Article
sources DOAJ
author Florent Allais
Jean Boivin
Van Tai Nguyen
spellingShingle Florent Allais
Jean Boivin
Van Tai Nguyen
Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
Beilstein Journal of Organic Chemistry
author_facet Florent Allais
Jean Boivin
Van Tai Nguyen
author_sort Florent Allais
title Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_short Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_full Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_fullStr Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_full_unstemmed Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_sort part 2. mechanistic aspects of the reduction of s-alkyl-thionocarbonates in the presence of triethylborane and air
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2007-12-01
description Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.
url https://doi.org/10.1186/1860-5397-3-46
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AT jeanboivin part2mechanisticaspectsofthereductionofsalkylthionocarbonatesinthepresenceoftriethylboraneandair
AT vantainguyen part2mechanisticaspectsofthereductionofsalkylthionocarbonatesinthepresenceoftriethylboraneandair
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