Aqueous Medium Preparation of Dialkyldiselenides
Abstract One-pot, two-step reaction conditions have been developed for the preparation of dialkyl diselenides by the treatment of alkyl halides with potassium selenocyanate followed by alkaline hydrolysis of the in situ generated alkyl selenocyanate in water. The reaction is reasonably fast and the...
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Georg Thieme Verlag KG
2018-07-01
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| Series: | SynOpen |
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| Online Access: | http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1610360 |
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doaj-be54c04e16b548588d3a189a419719092020-11-25T03:31:54ZengGeorg Thieme Verlag KGSynOpen2509-93962018-07-0102030229023310.1055/s-0037-1610360Aqueous Medium Preparation of DialkyldiselenidesTapasi MannaAnup Kumar MisraAbstract One-pot, two-step reaction conditions have been developed for the preparation of dialkyl diselenides by the treatment of alkyl halides with potassium selenocyanate followed by alkaline hydrolysis of the in situ generated alkyl selenocyanate in water. The reaction is reasonably fast and the yields of the products were very good. Several functional groups present in the substrates were unaffected under the reaction conditions.http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1610360seleniumalkyl halidesdimerizationsustainable chemistrywater |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Tapasi Manna Anup Kumar Misra |
| spellingShingle |
Tapasi Manna Anup Kumar Misra Aqueous Medium Preparation of Dialkyldiselenides SynOpen selenium alkyl halides dimerization sustainable chemistry water |
| author_facet |
Tapasi Manna Anup Kumar Misra |
| author_sort |
Tapasi Manna |
| title |
Aqueous Medium Preparation of Dialkyldiselenides |
| title_short |
Aqueous Medium Preparation of Dialkyldiselenides |
| title_full |
Aqueous Medium Preparation of Dialkyldiselenides |
| title_fullStr |
Aqueous Medium Preparation of Dialkyldiselenides |
| title_full_unstemmed |
Aqueous Medium Preparation of Dialkyldiselenides |
| title_sort |
aqueous medium preparation of dialkyldiselenides |
| publisher |
Georg Thieme Verlag KG |
| series |
SynOpen |
| issn |
2509-9396 |
| publishDate |
2018-07-01 |
| description |
Abstract
One-pot, two-step reaction conditions have been developed for the preparation of dialkyl diselenides by the treatment of alkyl halides with potassium selenocyanate followed by alkaline hydrolysis of the in situ generated alkyl selenocyanate in water. The reaction is reasonably fast and the yields of the products were very good. Several functional groups present in the substrates were unaffected under the reaction conditions. |
| topic |
selenium alkyl halides dimerization sustainable chemistry water |
| url |
http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1610360 |
| work_keys_str_mv |
AT tapasimanna aqueousmediumpreparationofdialkyldiselenides AT anupkumarmisra aqueousmediumpreparationofdialkyldiselenides |
| _version_ |
1724570939178352640 |